Hydride transfer reactions between penta- and tetra-coordinate silicon derivatives

DOI: 10.1016/0022-328X(92)80058-6

Source and publish data:

Journal of Organometallic Chemistry p. C1 - C5 (1992)

Update date:2022-08-30

Topics:

Authors:

Corriu, R.J.P.

Guerin, C.

Henner, B.J.L.

Wang, Q.

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Article abstract of DOI:10.1016/0022-328X(92)80058-6

K has been found to reduce Ph3SiF and Ph3SiCl and to induce H/D exchange with Ph3SiD and Ph2SiD2.The mechanism of this exchange seems to be a one-step concerted mechanism through an intermediate with bridging hydrogen and deuterium atoms.

Full text of DOI:10.1016/0022-328X(92)80058-6

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