The Question of 'Open' or 'Closed' Bimetallic Phosphinidene (and Heavier Congeneric) Complexes

DOI: 10.1039/c39850001267

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Journal of the Chemical Society. Chemical communications p. 1267 - 1268 (1985)

Update date:2022-08-17

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Authors:

Arif, Atta M.

Cowley, Alan H.

Norman, Nicholas C.

Orpen, A. Guy

Pakulski, Marek

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Article abstract of DOI:10.1039/c39850001267

The reaction of ArPCl2 (Ar = 2,4,6-Bu^t3-C6H2) with Na affords the 'open' phosphinidene complex, Co2(μ2-PAr)(ν-C5H5)2(CO)2, the structure of which has been determined by X-ray crystallography.

Full text of DOI:10.1039/c39850001267

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