Derivatives of a Weakly Basic Amine. N,N-Bis(2-fluoro-2,2-dinitroethyl)amine

Article abstract of DOI:10.1021/je00027a031

The use of S-ethyl carbonochloridothioate (2) as a chlorocarbonylation reagent for the preparation of N,N-bis(2-fluoro-2,2-dinitroethyl)carbamyl chloride (4) is described. 4 is a reactive intermediate which can be used to introduce the N,N-bis(2-fluoro-2,2-dinitroethyl)amino group into a variety of compounds.The preparation and some reactions of a number of these derivatives are presented.