Chemistry Letters p. 471 - 472 (1995)
Update date:2022-08-11
Topics:
Inaba, Minoru
Sawai, Ken
Ogumi, Zempachi
Takehara, Zen-ichiro
The dechlorination of 2-chloro-1,1,1,2-tetrafluoroethane (HCFC-124) was carried out electrochemically on a solid polymer electrolyte composite electrode (Pd-Neosepta).As the sole product 1,1,1,2-tetrafluoroethane (HFC-134a) was obtained.Irradiation with light of a xenon arc lamp enhanced the dissociation of C-Cl bond of the reactant adsorbed on Pd, resulting in an increase in the rate for HFC-134a formation.
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