A NEW "SWITCHED-ON" CROWN ETHER WHICH EXHIBITS A REVERSIBLE ALL-OR-NONE ION-BINDING ABILITY

DOI: 10.1016/S0040-4039(00)87401-8

Source and publish data:

Tetrahedron Letters p. 2581 - 2584 (1982)

Update date:2022-08-17

Topics:

Authors:

Shinkai, Seiji

Minami, Takahide

Kusano, Yumiko

Manabe, Osamu

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Article abstract of DOI:10.1016/S0040-4039(00)87401-8

A new photoresponsive crown ether (2) in which the poly(oxyethylene) chain is linked to 4- and 4' position of azobenzene was synthetized.Trans-(2) completely lacked the affinity to alkali metal cations, while photoisomerized cis-(2) was capable of binding

Full text of DOI:10.1016/S0040-4039(00)87401-8

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