Journal of the Chemical Society. Perkin transactions II p. 919 - 922 (1988)
Update date:2022-08-11
Topics:
Clark, David R.
Emsley, John
Hibbert, Frank
A value of φ 0.58+/-0.05 has been obtained for the deuterium fractionation factor of the hydrogen-bonded complex AcO(1-)...(HOAc)n from (1)H n.m.r. studies of solutions of potassium acetate in AcOH and 97percent AcOD-3percent AcOH.The result is used to account for the kinetic solvent isotope effect
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