Stereoselective Allylation of β-Hydroxy- and β-Amino-α,β-enones with Allyltrifluorosilane/Triethylamine Systems

Article abstract of DOI:10.1246/cl.1995.281

Reactions of allyltrifluorosilanes with β-functional-α,β-enones such as o-hydroxy- and o-aminophenyl ketones and 1,3-diketones in the presence of triethylamine yielded the corresponding tertiary homoallyl alcohols in regiospecific and highly diastereosele