Chemistry Letters p. 1529 - 1530 (1985)
Update date:2022-08-11
Topics:
Hosokawa, Takahiro
Makabe, Yoshiki
Shinohara, Toru
Murahashi, Shun-Ichi
(S)-(-)- and (R)-(+)-Frontalin were synthesized, respectively, in high enantiomer excess from β-methallyl alcohol (2) by three-step procedure; (i) asymmetric epoxidation of 2, (ii) the epoxide opening with homoallylmagnesium bromide, and (iii) Pd(II)-catalyzed intramolecular acetalization.
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(2018)Doi:10.1016/j.jorganchem.2018.11.020
(2019)Doi:10.1016/S0040-4039(02)00610-X
(2002)Doi:10.1063/1.436967
(1978)
