Chemistry Letters p. 1339 - 1342 (1990)
Update date:2022-08-29
Topics:
Masaki, Yasuhiro
Uehara, Yoshikazu
Yanagida, Shozo
Pac, Chyongjin
The isomerization of Hexamethyl (Dewar benzene) to hexamethylbenzene is photosensitized by 1,4-dicyanonaphthalene-arene exciplexes.Spectroscopic and quantum-yield studies suggest that the isomerization proceeds mostly through an adiabatic pathway from hypothetical termolecular excited complexes (triplexes).
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