Synthesis of dithio-, thio- and carbamoyl ester derivatives of monosaccharides and itols

Article abstract of DOI:10.1080/10426509808032452

Regiospecific carbamoylation of O-isopropylidene protected monosaccharides and itols gave a large range of novel carbamoyl, thiocarbamoyl and dithiocarbamoyl esters. These fully, partially and unprotected carbohydrates possess both modulable hydrophilic character and potential biological properties. Some carbamoyl esters showed, by NMR spectroscopy, characteristics of Z-E isomerism; the rotational energy barrier was higher for the thiocarbamates than for the corresponding carbamates.

Full text of DOI:10.1080/10426509808032452

This article was downloaded by: [Moskow State Univ Bibliote]
On: 02 December 2013, At: 06:55
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number: 1072954 Registered office:
Mortimer House, 37-41 Mortimer Street, London W1T 3JH, UK
Phosphorus, Sulfur, and Silicon and the
Related Elements
Publication details, including instructions for authors and subscription
information:
http://www.tandfonline.com/loi/gpss20
SYNTHESIS OF DITHIO-, THIO-AND
CARBAMOYL ESTER DERIVATIVES OF
MONOSACCHARIDES AND ITOLS
Christophe Len a , Denis Postel a , Gino Ronco a & Pierre Villa a
a Laboratoire de Chimie Organique et Cinétique , Université de Picardie-
Jules Verne , 33, rue Saint Leu, 80039, Amiens, France
Published online: 24 Sep 2006.
To cite this article: Christophe Len , Denis Postel , Gino Ronco & Pierre Villa (1998) SYNTHESIS OF
DITHIO-, THIO-AND CARBAMOYL ESTER DERIVATIVES OF MONOSACCHARIDES AND ITOLS, Phosphorus, Sulfur,
and Silicon and the Related Elements, 133:1, 41-59, DOI: 10.1080/10426509808032452
To link to this article: http://dx.doi.org/10.1080/10426509808032452
PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of all the information (the
“Content”) contained in the publications on our platform. However, Taylor & Francis, our
agents, and our licensors make no representations or warranties whatsoever as to the
accuracy, completeness, or suitability for any purpose of the Content. Any opinions and views
expressed in this publication are the opinions and views of the authors, and are not the views
of or endorsed by Taylor & Francis. The accuracy of the Content should not be relied upon
and should be independently verified with primary sources of information. Taylor and Francis
shall not be liable for any losses, actions, claims, proceedings, demands, costs, expenses,
damages, and other liabilities whatsoever or howsoever caused arising directly or indirectly in
connection with, in relation to or arising out of the use of the Content.
This article may be used for research, teaching, and private study purposes. Any substantial
or systematic reproduction, redistribution, reselling, loan, sub-licensing, systematic supply, or
distribution in any form to anyone is expressly forbidden. Terms & Conditions of access and
use can be found at http://www.tandfonline.com/page/terms-and-conditions