Journal of the Chinese Chemical Society p. 861 - 863 (1999)
Update date:2022-08-18
Topics:
Wu, Yuh-Wern
Tseng, Ming-Chung
Lu, Cheng-Yi
Chou, Hsueh-Hsun
Tseng, Yeong-Fuh
Hsieh, Hui-Joan
The relative rates of the leaving groups in free radical SH2′ reactions have been determined. The order of the relative elimination rates of the leaving group is: I > Br (14) > SPh (2) > Cl (1) ? OPh, SiMe3. This is consistent with the bond dissociation energy of the C-X bond. The less the bond dissociation energy value is, the better the leaving group is.
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