Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 2807 - 2814 (1982)
Update date:2022-08-16
Topics:
Pawlak, Zenon
Magonski, Jozef
The dissociation constants of eight phenols and homoconjugation constants of the corresponding phenol-phenolate systems in propylene carbonate were determined from e.m.f. measurements.The results are compared with those obtained previously in acetonitrile and acetone.The effect of the nitro-group on the decrease of the homoconjugation constant is found to be much greater than that of the chloro-substituent.In general, the stability of the homocomplexes insreases with the pKa value of the phenol.
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