Journal of Fluorine Chemistry p. 57 - 61 (2000)
Update date:2022-08-17
Topics:
Ignat'ev, Nikolai
Sartori, Peter
The electrochemical fluorination (ECF) of trialkylphosphines results in the formation of the corresponding tris(perfluoroalkyl)difluorophosphoranes in good yield. In the case of ECF of tri(iso-butyl)phosphine, isomerisation of iso- into n-alkyl compound occurs.
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