Tetrahedron Letters p. 8485 - 8488 (1993)
Update date:2022-08-29
Topics:
Takano
Moriya
Kamikubo
Hiroya
Ogasawara
It has been revealed that the generation of 2-cyclohexenones from cis- 1,4-dihydroxycyclohexene derivatives under PdCl2(PPh3)2-HCO2NH4 system takes place in an intramolecular pathway involving unprecedented mode of suprafacial 1,4-hydrogen migration across the 1,4-allylic centers.
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