Journal of Fluorine Chemistry p. 279 - 284 (1993)
Update date:2022-08-11
Topics:
Duan, Jian-Xing
Su, De-Bao
Chen, Qing-Yun
Treatment of methyl halodifluoroacetates, XCF2CO2Me (X=Cl, Br, I), with organic halides RY in the presence of KF and CuI at an appropriate temperature in DMF gave the corresponding trifluoromethylated derivatives, RCF3, in moderate to high yields.A process involving difluorocarbene and trifluoromethide intermediates is suggested.
View More
Zhejiang Haizhou Pharmaceutical Co., Ltd.
website:https://www.haizhoupharma.com/
Contact:+86-576-88221016
Address:No. 19, Donghai 5th Avenue, Yanhai Industrial Zone, Linhai, Zhejiang, China
Tianjin Hedong Red Cliff Chemical Reagent Factory
Contact:+86-022-84780548
Address:Li Ming Zhuang Gong Ye Yuan,Dongli District,Tianjin,China
Wuhan Hanye Chemical New Material Co.,Ltd
Contact:+86-27-85308141
Address:LiuDian, Panlongcheng Economic Development Zone, HuangPi district, Wuhan, Hubei 430311 P.R.China
Shanghai Pinewood Fine Chemical Co., Ltd.
website:http://www.pinewoodchem.com
Contact:0086-21-62417129，62414096
Address:Suite B, 27F, No.2, Lane 600, Tianshan Road, Shanghai
Jiangsu Zenji Pharmaceuticals LTD
Contact:+86-025-83172562; +1-224-888-1133(USA)
Address:No.5 Xinmofan Road
Doi:10.1007/s11172-010-0164-6
(2010)Doi:10.1002/jhet.3591
(2019)Doi:10.1016/S0022-3697(01)00192-5
(2002)Doi:10.1021/ic061752i
(2007)Doi:10.1021/j100339a033
(1989)Doi:10.1055/s-0033-1341228
(2014)
