Journal of Organic Chemistry p. 2142 - 2146 (1987)
Update date:2022-08-16
Topics:
Tanner, Dennis D.
Singh, Harrbansh Kumar
Kharrat, Abdelmajid
Stein, Allan R.
The mechanism for the reduction of the α-haloacetophenones by four dihydronicotinamides (DHNA's) procceds by free radical chain whose initiation and propagation sequences both contain single electron transfer reactions.The use of DHNA's as models for the role of NADH in enzyme-mediated reductions is discussed.
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