Journal of the Chemical Society. Chemical communications p. 317 - 319 (1982)
Update date:2022-08-11
Topics:
Mansuy, Daniel
Fontecave, Marc
Battioni, Jean-Paul
Formation of the ?-alkyl FeIII (TPP)(CH2C6H4NO2-4) complex (TPP = tetraphenylporphyrin) during reduction of 4-nitrobenzyl chloride (1) by sodium ascorbate catalysed by Fe(TPP)(Cl) was detected by visible spectroscopy, and its involvement as an intermediate in the reduction of (1) to 4-nitrotoluene was deduced from a study of the characteristics of this reaction.
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