Basic Information | Post buying leads | Suppliers | Cas Database |
Conditions | Yield |
---|---|
With quinoline; oct-1-ene; hydrogen; Lindlar's catalyst | A 98.3% B 1.7% |
With hydrogen; silica gel; rhodium(1+) In ethanol; toluene at 40℃; under 1320.1 Torr; Product distribution; | A 32% B 1% |
With hydrogen; copper at 200℃; |
6-iodohept-1-ene
A
1-Heptene
B
1-(iodomethyl)-2-methylcyclopentane
C
cis-1,2-dimethylcyclopentane
trans-1,2-dimethylcyclopentane
Conditions | Yield |
---|---|
With lithium triethylborohydride In tetrahydrofuran for 2h; Product distribution; Mechanism; or with deuterated dicyclohexylphosphine (DCPD) or other reagents; | A 98% B 9% C n/a D n/a |
Conditions | Yield |
---|---|
TR97305 at 300℃; Dehydrochlorination; | 97% |
Conditions | Yield |
---|---|
With triphenylphosphine; copper dichloride In tetrahydrofuran at 60℃; | 96% |
1-Heptene
Conditions | Yield |
---|---|
Cu(acac)2-PPh3 In tetrahydrofuran | 95% |
Conditions | Yield |
---|---|
With hydrogen at 40℃; under 3000.3 Torr; for 0.333333h; Kinetics; Reagent/catalyst; Temperature; | 93% |
With piperazine; hydrogen In ethanol at 80℃; under 4500.45 Torr; for 24h; | 90% |
With methanol; hydrogen; nickel Hydrogenation; |
Conditions | Yield |
---|---|
With bis(cyclopentadienyl)titanium dichloride; magnesium In tetrahydrofuran for 12h; Ambient temperature; | 92% |
Conditions | Yield |
---|---|
With Grubbs catalyst first generation In toluene at 40℃; under 3750.38 Torr; for 0.5h; Temperature; Reagent/catalyst; Pressure; Inert atmosphere; Glovebox; Sealed tube; | 91.3% |
With 1-Propyl acetate; ethylaluminum dichloride; tungsten(VI) oxychloride diethyl etherate In toluene at 85℃; under 2850.29 - 3000.3 Torr; for 2h; |
Conditions | Yield |
---|---|
With hydrogen; palladium dichloride In N,N-dimethyl-formamide under 18751.5 Torr; for 0.416667h; Product distribution; Ambient temperature; various time; | A 89% B 1.8% C 2.9% D 6.3% |
1-chloromethanesulfonyl-hexane
1-Heptene
Conditions | Yield |
---|---|
With sodium hydroxide; Aliquat 336 In dichloromethane for 30h; Heating; | 85% |
Chemistry informtion about 1-Heptene (592-76-7) is:
IUPAC Name: Hept-1-ene
Synonyms: 1-C7H14 ; 1-n-Heptene ; Alpha-heptylene ; Hept-1-ene;Heptylene ; N-hept-1-ene ; N-heptene ; Heptene-1.
MF: C7H14
MW: 98.19
EINECS: 209-767-8
Melting Point: −119 °C(lit.)
Boiling Point: 94 °C(lit.)
Flash Point: 16 °F
Refractive Index: n20/D 1.400(lit.)
Density: 0.697 g/ml at 25 °C(lit.)
Enthalpy of Vaporization: 31.9 kJ/mol
Vapour Pressure: 57.1 mmHg at 25°C
BRN: 1098332
Storage temp. : Flammables area
Following is the molecular structure of 1-Heptene (592-76-7) is:
Poisoning
Hazard Codes:
F: Flammable
Xn: Harmful
Risk Statements:
R11: Highly flammable.
R36/37/38: Irritating to eyes, respiratory system and skin.
R65: Harmful, may cause lung damage if swallowed.
Safety Statements:
S16: Keep away from sources of ignition.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36: Wear suitable protective clothing.
S62: If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label.
RIDADR: UN 2278 3/PG 2
WGK Germany: 1
RTECS: MJ8840000
F: 10 Keep under argon.
HazardClass: 3
PackingGroup: II
1-Heptene (592-76-7) is a clear colorless liquid.
First aid measures:
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Get medical aid. Wash mouth out with water.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Handling and Storage:
Handling: Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage: Keep away from sources of ignition. Store in a cool, dry place. Keep container closed when not in use. Flammables-area.