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| CAS No.: | 593-71-5 |
|---|---|
| Name: | Chloroiodomethane |
| Molecular Structure: | |
|
|
|
| Formula: | CH2ClI |
| Molecular Weight: | 176.384 |
| Synonyms: | chloro-iodo-methane; |
| EINECS: | 209-804-8 |
| Density: | 2.343 g/cm3 |
| Boiling Point: | 102.2 °C at 760 mmHg |
| Flash Point: | 15.6 °C |
| Appearance: | clear pale yellow to pink-reddish liquid |
| Hazard Symbols: |
 Xi
|
| Risk Codes: | 36/37/38 |
| Safety: | 26-36-24/25-23 |
| Transport Information: | UN 2810 |
| PSA: | 0.00000 |
| LogP: | 1.61770 |
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| Conditions | Yield |
|---|---|
| With iodine trichloride Product distribution; further iodoalkanes; | A 34% B 50% |
| Conditions | Yield |
|---|---|
| With aluminium trichloride; potassium chloride at 114℃; |
| Conditions | Yield |
|---|---|
| With pyridine; tributyltin chloride at 100℃; Thermodynamic data; Equilibrium constant; Δ G; | |
| With Iodine monochloride | |
| With Iodine monochloride |
| Conditions | Yield |
|---|---|
| With methanol; sodium iodide | |
| With methanol; sodium iodide at 130℃; | |
| With methyl iodide; Wilkinson's catalyst at 100℃; for 2h; | |
| With methyl iodide; tris(triphenylphosphine)ruthenium(II) chloride at 100℃; for 2h; |
- 17305-95-2
(chloromethyl)mercury(II) chloride
- 593-71-5
Chloroiodomethane
| Conditions | Yield |
|---|---|
| With iodine |
| Conditions | Yield |
|---|---|
| With Amberlyst A-26 (chloride form); methyl iodide at 27 - 70℃; for 9h; Yield given. Yields of byproduct given; |
- 16519-98-5
iodomethyl
- 593-71-5
Chloroiodomethane
| Conditions | Yield |
|---|---|
| With chlorine Rate constant; Thermodynamic data; Irradiation; poly(tetrafluoroethylene)-coated Pyrex or uncoated quartz reactor, temperatures 295 - 524 K; |
| Conditions | Yield |
|---|---|
| neutral alumina 90 + Bu4P(1+)I(1-) In gas at 195℃; under 760 Torr; for 1.25h; | A 36 % Spectr. B 50 % Spectr. |
| neutral alumina 90 + Bu4P(1+)I(1-) In gas at 195℃; under 760 Torr; | A 9 % Spectr. B 34 % Spectr. |
- 593-71-5
Chloroiodomethane
| Conditions | Yield |
|---|---|
| With iodine; potassium iodide |
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hydrogen iodide
A
- 593-71-5
Chloroiodomethane
B
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iodomethylbenzene
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Chemistry
IUPAC:chloro(iodo)methane
CAS:593-71-5
The Molecular formula of Chloroiodomethane(593-71-5):CH2ClI
The Molecular Weight of Chloroiodomethane(593-71-5):176.38
Synonyms:METHYLENE CHLOROIODIDE;CHLOROIODOMETHANE;Methane, chloroiodo-;CHLOROIODOMETHANE, STAB.;Chloroiodomethane,98%; Chloroiodomethane, stabilized, 98%;CHLOROIODOMETHANE , STABILIZED WITH COPPER;Chloroiodomethane, 98%, stab. with copper
EINECS:209-804-8
Density:2.422 g/mL at 25oC(lit.)
Boiling Point:108-109oC(lit.)
Flash Point:15.6oC
Vapour Pressure:39.3 mmHg at 25oC
Refractive index:n20/D 1.582(lit.)
storage temp.:0-6oC
Product Categories:Aliphatics;Halides;Alcohol& Phenol& Ethers;omega-Functional Alkanols, Carboxylic Acids, Amines & Halides;omega-Haloalkyl Chlorides;Alkyl;Halogenated Hydrocarbons;Organic Building Blocks
Mol File:593-71-5.mol
Uses
Safety Profile
Hazard Codes:Xi
Risk Statements:36/37/38
36/37/38(Irritating to eyes, respiratory system and skin)
Safety Statements:26-36-24/25-23
26(In case of contact with eyes, rinse immediately with plenty of water and seek medical advice)
36(Wear suitable protective clothing)
24/25(Avoid contact with skin and eyes)
23(Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer))
RIDADR:UN2810
WGK Germany:3
F:8
HazardClass:6.1
Specification
Storage:Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Refrigerator (approx 4oC). Store protected from light.
Handling:Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Store protected from light.