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Conditions | Yield |
---|---|
With carbon monoxide; rhodium(I) acetylacetonate; hydrogen; triphenylphosphine In toluene at 100℃; under 10343.2 Torr; for 2h; Autoclave; | 81% |
Conditions | Yield |
---|---|
With pyridine chromium peroxide In dichloromethane for 1.25h; Ambient temperature; | 99% |
With polymeric complex of oxodiperoxochromium(VI) compound and pyrazine (Pyz-CrO5)n In dichloromethane for 1.5h; Ambient temperature; | 99% |
With pyridine chromium peroxide In dichloromethane for 1.25h; Product distribution; Ambient temperature; effect of various chromium(VI) based oxidants; | 99% |
Conditions | Yield |
---|---|
With 1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane tribromide In methanol; dichloromethane at 20℃; for 0.1h; | 97% |
With iodosylbenzene In dichloromethane at 20℃; for 0.416667h; | 95% |
With silica gel In neat (no solvent) at 20℃; for 0.0833333h; | 93% |
With Clayan for 0.05h; Irradiation; microwave irradiation; | 81% |
Conditions | Yield |
---|---|
With synthesis gas; dicarbonylacetylacetonato rhodium (I); C44H33BrN2P2 In 5,5-dimethyl-1,3-cyclohexadiene at 150℃; under 7500.75 - 30003 Torr; for 3h; Autoclave; Inert atmosphere; | 96.3% |
Conditions | Yield |
---|---|
With oxidase In water at 40℃; for 1.5h; Reformatsky Reaction; | 100% |
With oxygen In neat (no solvent) at 45℃; for 7h; Solvent; Temperature; | 50 %Chromat. |
Conditions | Yield |
---|---|
With hydrogen In octane at 400℃; under 760.051 Torr; for 6h; Reagent/catalyst; | A 36.6% B 15.3% C 7.6% |
Conditions | Yield |
---|---|
With sodium periodate; [η5-C5H5Ru(CO)2NH2C6H11]BF4 In water; acetonitrile at 60℃; for 3h; Catalytic behavior; Schlenk technique; Inert atmosphere; | 98% |
With sodium periodate; C53H44As2N2O3Ru In water; ethyl acetate; acetonitrile at 25℃; for 0.5h; | 98% |
With sodium periodate; C18H14Cl3N2Ru(1+)*F6P(1-) In water; tert-butyl alcohol at 60℃; for 1h; Catalytic behavior; Inert atmosphere; Schlenk technique; | 91% |
Conditions | Yield |
---|---|
With dihydrogen peroxide; bromine In hexane; water at 20℃; for 24h; | A 9% B 91% |
With pyridine; 4-acetylamino-2,2,6,6-tetramethylpiperidine-N-oxyl; iodine; sodium hydrogencarbonate In dichloromethane; water at 20 - 25℃; for 3h; | A 12.9% B 87.1% |
With chloro-tris-(2-methoxy-phenyl)-methane In dichloromethane for 9h; Ambient temperature; | A 28% B 57% |
With chromium(VI) oxide; aluminum oxide In hexane for 15h; Ambient temperature; | A 47% B 48% |
With 4-acetylamino-2,2,6,6-tetramethyl-1-piperidinoxy; iodine; sodium hydrogencarbonate In dichloromethane; water at 20 - 22℃; for 3h; | A 36 %Chromat. B 22 %Chromat. |
1,1-diacetoxy-heptane
heptanal
Conditions | Yield |
---|---|
With 2,6-dicarboxypyridinium chlorochromate In acetonitrile at 20℃; for 0.25h; | 96% |
With tetra-N-butylammonium tribromide In methanol at 20℃; for 0.25h; | 95% |
With carbon tetrabromide In acetonitrile for 3h; Heating; | 87% |
Conditions | Yield |
---|---|
With dihydrogen peroxide; tetra(n-butyl)ammonium hydrogensulfate; sodium tungstate In tert-butyl alcohol at 90℃; | A 11% B 89% |
With 1-methyl-3-(2-oxo-2-(2,2,6,6-tetramethyl-1-ylooxy-4-piperidoxyl)ethyl)imidazolium chloride; 1-(carboxymethyl)-3-methylimidazolium chloride; oxygen; sodium nitrite In water at 59.84℃; under 7500.75 Torr; for 12h; Inert atmosphere; | A 76% B 12% |
With C30H24N2O7W; dihydrogen peroxide In water; acetonitrile for 17h; Reflux; | A 72% B 17% |
1. | orl-rat LD50:14 g/kg | FDRLI* Food and Drug Research Labs., Papers .(Waverly, NY.: )1976,123. | ||
2. | orl-mus LD50:20 g/kg | BIJOAK Biochemical Journal. 34 (1940),1196. |