Basic Information | Post buying leads | Suppliers | Cas Database |
Conditions | Yield |
---|---|
With 4 A molecular sieve; tetrabutylammonium periodite; sodium ruthenate(VI) In dichloromethane at 20℃; for 24h; Oxidation; | 100% |
With 4 A molecular sieve; tetrabutylammonium perchlorate; Ru-Cu-Al-hydrotalcite In toluene at 60℃; for 24h; | 100% |
With iodosylbenzene; Cl-CH2-PS supported 5-amino-1,10-phenanthroline-Ru In acetonitrile at 60℃; for 2h; | 100% |
Conditions | Yield |
---|---|
With water In tetrahydrofuran; diethyl ether at 80℃; under 6000.6 Torr; Inert atmosphere; Autoclave; | 100% |
With dibromotriphenylphosphorane In dichloromethane at -50℃; for 1h; | 74% |
With 6C72H112O8*8H2O In chloroform-d1; water for 1h; Inert atmosphere; |
1,1-hexanediol diacetate
hexanal
Conditions | Yield |
---|---|
With beta zeolite modified with chlorosulphonic acid (28 wtpercent) In ethanol at 50℃; for 0.0833333h; | 100% |
With ethanol at 50℃; for 0.166667h; chemoselective reaction; | 98% |
With (NH4)3PW12O40 In methanol at 20℃; for 2h; | 92% |
Conditions | Yield |
---|---|
With water In tetrahydrofuran; diethyl ether at 80℃; under 6000.6 Torr; Inert atmosphere; Autoclave; | 100% |
Conditions | Yield |
---|---|
With thexylchloroborane-Me2SO4 In dichloromethane for 0.25h; Ambient temperature; | 99% |
With thexylchloroborane-Me2SO4 In dichloromethane for 0.25h; Product distribution; Ambient temperature; other aliphatic and aromatic acids, other products, other times; | 99% |
With thexylbromoborane dimethyl sulfide complex In carbon disulfide; dichloromethane at -20 - 20℃; for 1h; | 94% |
hexanoic acid Li-salt
hexanal
Conditions | Yield |
---|---|
With 9-borabicyclo[3.3.1]nonane dimer In tetrahydrofuran for 1h; Ambient temperature; | 99% |
Conditions | Yield |
---|---|
With hydrogen; sodium dodecyl-sulfate; palladium diacetate In tetrahydrofuran; water at 20℃; under 760.051 Torr; for 0.5h; Reagent/catalyst; chemoselective reaction; | 98% |
With N,N,N,N,N,N-hexamethylphosphoric triamide; diisobutylaluminium hydride In tetrahydrofuran; hexane at 0℃; for 1h; | 89% |
With hydrogen In isopropyl alcohol at 110℃; under 22502.3 Torr; for 3h; Autoclave; | 35.2% |
N-methoxy-N-methyl hexanamide
hexanal
Conditions | Yield |
---|---|
With lithium diisobutyl-tert-butoxyaluminum hydride In tetrahydrofuran; hexane at 0℃; Reagent/catalyst; Inert atmosphere; chemoselective reaction; | 97% |
With benzoic acid ethyl ester; copper diisobutyl-t-butoxyaluminum hydride In tetrahydrofuran at 20℃; for 12h; Inert atmosphere; chemoselective reaction; | 99 %Chromat. |
Conditions | Yield |
---|---|
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium hydrogencarbonate; sodium bromide In dichloromethane; water at 0℃; Electrolysis; Saturated solution; | A n/a B 95% |
With calcium dichloride dihydrate; oxone; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; water In dichloromethane at 20℃; for 2.5h; Catalytic behavior; Reagent/catalyst; Time; Solvent; Overall yield = 59 %Chromat.; | A 91% B 9% |
With oxone; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; tetrabutylammomium bromide; water In dichloromethane at 20℃; for 4h; Catalytic behavior; Overall yield = 7 %Chromat.; | A 9% B 52% |
isopropyl amyl carbinol
hexanal
Conditions | Yield |
---|---|
With lead(IV) acetate; lithium chloride In benzene at 80℃; | 95% |
1. | skn-rbt 500 mg/24H MLD | 85JCAE Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,272. | ||
2. | skn-rbt 14,178 μg/24H open MLD | AIHAAP American Industrial Hygiene Association Journal. 23 (1962),95. | ||
3. | eye-rbt 500 mg/24H MLD | 85JCAE Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,272. | ||
4. | orl-rat LD50:4890 mg/kg | AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61. | ||
5. | ihl-rat LCLo:2000 ppm/4H | AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61. |