Welcome to LookChem.com Sign In|Join Free
  • or
Home > Products >  > 

Lanthanum(III) chloride

Related Products

Hot Products

Name

Lanthanum(III) chloride

EINECS 233-237-5
CAS No. 10099-58-8 Density 3.84 g/mL at 25 °C(lit.)
PSA 0.00000 LogP 2.06850
Solubility Soluble in water. Melting Point 860 °C(lit.)
Formula Cl3La Boiling Point 1812 °C(lit.)
Molecular Weight 245.264 Flash Point 1000oC
Transport Information UN 3264 Appearance white powder or colourless crystals
Safety 26-36 Risk Codes 36/37/38-11
Molecular Structure Molecular Structure of 10099-58-8 (Lanthanum(III) chloride) Hazard Symbols IrritantXi
Synonyms

Lanthanum chloride (La2Cl6);Lanthanum trichloride;Lanthanum chloride;

Article Data 113

Lanthanum(III) chloride Synthetic route

lanthanum tert-butoxycuprate

A

lanthanum(III) chloride

lanthanum(III) chloride

B

copper(l) chloride

Conditions
ConditionsYield
With HCl In tetrahydrofuran gaseous HCl was condensed into soln. of La complex in THF to result in a formation of finely dispersed ppt.; ppt. of CuCl sepd. by centrifugation, washed with water under Ar, driedin vacuo at 50°; aq. soln. evapd. to dryness to give LaCl3; products identified by elem. anal.;A 96.8%
B 99%

([La(μ-Cl)(H2O)7](Cl)2)2

10099-58-8

lanthanum(III) chloride

Conditions
ConditionsYield
In neat (no solvent, solid phase) byproducts: H2O; Schlenk techniques; heating La compd. under vacuum (1E-3 Torr);99%
7647-01-0

hydrogenchloride

lanthanum(III) oxide

10099-58-8

lanthanum(III) chloride

Conditions
ConditionsYield
In hydrogenchloride metal oxide treated with 1:1 hydrochloric acid; soln. filtered, evapd. to dryness, crystals dried in vaccum dessicator over CaCl2;85%
In hydrogenchloride soln. evapd., dissolved (distd. water), again evapd. and dissolved (distd. water; pH adjusted to 5;
In hydrogenchloride

lanthanum(III) oxide

erbium(III) oxide

potassium chloride

7782-50-5

chlorine

A

10138-41-7

erbium(III) chloride

B

10099-58-8

lanthanum(III) chloride

Conditions
ConditionsYield
With pyrographite In gas byproducts: CO; by chlorination-chem. vapor transport react.; mixt. of Er2O3 and La2O3 with carbon and KCl (1:1:6:1 at. ratio) placed in alumina reactor and chlorinated with dry Cl2 (20 cm**3/min) at 800 K for 2 h; gas replace by Ar:Cl2 at 800-1300 K; detn. of separation factor;A 36.89%
B 24.85%

lanthanum(III) oxide

aluminium chloride dimer

A

aluminum oxochloride

B

10099-58-8

lanthanum(III) chloride

Conditions
ConditionsYield
In neat (no solvent) Al2Cl6 prepd. from Al and Cl2; in Duran tube, at 500°C (Cl2); chemical vapour phase transport with Al2Cl6 from 500 to 400°C, 24 h;A n/a
B 8%
Kinetics; 622-793 K;

lanthanum(III) oxide

ammonium chloride

10099-58-8

lanthanum(III) chloride

Conditions
ConditionsYield
in inert gas at 200-400°C; quant. reaction requires a fourfold excess of NH4Cl;>99
In neat (no solvent) absence of moisture; large excess NH4Cl, evacuated quartz tube, 500-600 K; sublimation off of excess NH4Cl (vac., 700 K);
In not given byproducts: NH3, H2O; reaction at 650 K; sublimation at 1300 K for 8 h;
7647-01-0

hydrogenchloride

lanthanum(III) oxide

ammonium chloride

10099-58-8

lanthanum(III) chloride

Conditions
ConditionsYield
In hydrogenchloride mixed, decompn.;
In not given purified twice by sublimation in Ta tube;
La2O3 reacted with HCl and NH4Cl; dried under dynamic vac., sublimed;

lanthanum(III) chloride hydrated

10099-58-8

lanthanum(III) chloride

Conditions
ConditionsYield
With NH4Cl In neat (no solvent) heating of LaCl3*99H2O in the presence of NH4Cl (Handbuch der preparativen anorganischen Chemie, Herausg. G. Brauer, Studgardt, 1975);

lanthanum(III) chloride hexahydrate

10099-58-8

lanthanum(III) chloride

Conditions
ConditionsYield
In diethyl ether under inert gas, ether - acid drying, finally dried at 190 °C under vacuum;

lanthanum(III) oxide

10099-58-8

lanthanum(III) chloride

Conditions
ConditionsYield
With hydrogenchloride reaction of the oxide with HCl gas at 274-600°C;
With hydrogenchloride In hydrogenchloride La2O3 dissolved in concd. HCl; soln. evapd., residual chloride purified by high-temperature react. with NH4Cl (J.Kutscher and A.Schneider, Z.Anorg.Allg.Chem., 389 (1972) 157);
With ammonium chloride In hydrogenchloride mixture was coprecipitated and subsequently heated at 700 K in vacuum;

Lanthanum(III) chloride Consensus Reports

Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Lanthanum(III) chloride Specification

The Lanthanum(III) chloride, with the CAS registry number 10099-58-8,is also known as Lanthanum chloride,anhydrous. It belongs to the product categories of Inorganics;Catalysis and Inorganic Chemistry;Chemical Synthesis. This chemical's molecular formula is LaCl3 and molecular weight is 245.26.Its EINECS number is 233-237-5. What's more,Its systematic name is Lanthanum chloride. It is a white powder or colourless crystals.And it is irritating to eyes, respiratory system and skin .When you use it ,wear suitable protective clothing .In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Physical properties about Lanthanum(III) chloride are:
(1)ACD/LogP:  0; (2)# of Rule of 5 Violations:  0; (3)ACD/LogD (pH 5.5):  0.00; (4)ACD/LogD (pH 7.4):  0.00; (5)ACD/BCF (pH 5.5):  1.00; (6)ACD/BCF (pH 7.4):  1.00; (7)#H bond acceptors:  0; (8)#H bond donors:  0; (9)#Freely Rotating Bonds:  0; (10)Enthalpy of Vaporization:  16.15 kJ/mol; (11)Vapour Pressure:  33900 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES:Cl[La](Cl)Cl;
(2)Std. InChI:InChI=1S/3ClH.La/h3*1H;/q;;;+3/p-3;
(3)Std. InChIKey:ICAKDTKJOYSXGC-UHFFFAOYSA-K.

Uses of Lanthanum(III) chloride:
Lanthanum(III) chloride can be used to remove phosphates in swimming pools, which helps prevent algae growth. It is also used in biochemical research to block the activity of divalent cation channels, mainly calcium channels. Doped with cerium, it is used as a scintillator material. It is used as a mild Lewis acid to perform chemical reactions that usually require acidic conditions, such as converting aldehydes to acetals, under nearly neutral conditions.

The toxicity data of Lanthanum(III) chloride are as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
frog LD50 intraperitoneal 694mg/kg (694mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
guinea pig LD50 intraperitoneal 129mg/kg (129mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: FOOD INTAKE (ANIMAL)
AMA Archives of Industrial Health. Vol. 15, Pg. 9, 1957.
mouse LD50 intraperitoneal 121mg/kg (121mg/kg)   Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. Vol. 256, Pg. 1043, 1963.
mouse LD50 intravenous 18mg/kg (18mg/kg) LIVER: OTHER CHANGES Journal of the National Cancer Institute. Vol. 13, Pg. 559, 1952.
mouse LD50 subcutaneous 2424mg/kg (2424mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rabbit LD50 intravenous 148mg/kg (148mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rat LD50 intraperitoneal 106mg/kg (106mg/kg)   AMA Archives of Industrial Health. Vol. 16, Pg. 475, 1957.
rat LD50 oral 4184mg/kg (4184mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rat LDLo intravenous 4mg/kg (4mg/kg)   AMA Archives of Industrial Health. Vol. 16, Pg. 475, 1957.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 10099-58-8