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Name	Manganese acetylacetonate	EINECS	237-858-2
CAS No.	14024-58-9	Density	1,6 g/cm³
PSA	68.28000	LogP	1.10900
Solubility	Soluble in water	Melting Point	248-250 °C (dec.)(lit.)
Formula	C10H14 Mn O4	Boiling Point	138.4 °C at 760 mmHg
Molecular Weight	253.157	Flash Point	43.1 °C
Transport Information	N/A	Appearance	tan or light brown crystalline powder
Safety	Questionable carcinogen with experimental neoplastigenic and tumorigenic data. When heated to decomposition it emits acrid smoke and irritating fumes. See also MANGANESE COMPOUNDS.	Risk Codes	20/21/22-36/37/38-40
Molecular Structure		Hazard Symbols	Xn
Synonyms	Manganese,bis(2,4-pentanedionato)- (6CI,8CI); Manganese, bis(2,4-pentanedionato-O,O')-;Manganese, bis(2,4-pentanedionato-kO,kO')- (9CI); Acetylacetonemanganese(II); Bis(2,4-pentanedionato)manganese; Bis(acetylacetonato)manganese;Bis(acetylacetonato)manganese(II); Bis(acetylacetone)manganese; Manganesebis(2,4-pentanedionate); Manganese bis(acetylacetonate); Manganesediacetylacetonate; Manganese(2+) acetylacetonate; Manganese(II)acetylacetonate; Manganese(II) bis(acetylacetonate); Manganous acetylacetonate;NSC 177707; NSC 4656; NSC 52334	Article Data	4

Manganese acetylacetonate Chemical Properties

IUPAC: Manganese(2+); (Z)-4-oxopent-2-en-2-olate
Manganese acetylacetonate (14024-58-9) is also called for AI3-60152 ; Acetylacetone manganese(II) ; Bis(2,4-pentanedionato)manganese ; Bis(acetylacetonato)manganese(II) ; Bis(acetylacetone)manganese ; EINECS 237-858-2 ; Manganese bis(2,4-pentanedionate) ; Manganese bis(acetylacetonate) ; Manganese diacetoacetate ; Manganese(2+) acetylacetonate ; Manganese(II) acetylacetonate ; Manganese(II) bis(acetylacetonate) ; Manganous acetylacetonate ; NSC 177707 and so on.
Molecular Formula: C₁₀H₁₄MnO₄
Molecular Weight: 253.15
EINECS: 237-858-2
LogP: ACD/LogP: 0.29
ACD/LogD (pH 5.5): 0.29
ACD/LogD (pH 7.4): 0.25
ACD/BCF (pH 5.5): 1
ACD/BCF (pH 7.4): 1
ACD/KOC (pH 5.5): 34.16
ACD/KOC (pH 7.4): 31.16
H bond acceptors: 2
H bond donors: 1
Freely Rotating Bonds: 2
Heavy Atom Count: 15
Formal Charge: 0
Complexity: 90.4
Isotope Atom Count: 0
Defined Atom StereoCenter Count: 0
Undefined Atom StereoCenter Count: 0
Defined Bond StereoCenter Count: 2
Undefined Bond StereoCenter Count: 0
Covalently-Bonded Unit Count: 3
Flash Point: 71.9°C
Enthalpy of Vaporization: 49.32 kJ/mol
Boiling Point: 187.6°C at 760 mmHg
Vapour Pressure: 0.174 mmHg at 25°C
The molecular structure of Manganese acetylacetonate (14024-58-9):

Manganese acetylacetonate Uses

Manganese acetylacetonate (14024-58-9) is used as catalyst for organic synthesis.

Manganese acetylacetonate Toxicity Data With Reference

ims-rat TDLo:1200 mg/kg/26W-I:NEO

JNCIAM Journal of the National Cancer Institute. 60 (1978),1171.

Manganese acetylacetonate Consensus Reports

Manganese and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Manganese acetylacetonate Safety Profile

Questionable carcinogen with experimental neoplastigenic and tumorigenic data. When heated to decomposition it emits acrid smoke and irritating fumes. See also MANGANESE COMPOUNDS.
Hazard Codes: Xn Harmful
Risk Statements: 20/21/22-36/37/38-40
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
R40:Limited evidence of a carcinogenic effect.
Safety Statements: 26-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
WGK Germany: 3
RTECS: OO9350000
TSCA: Yes

Manganese acetylacetonate Standards and Recommendations

OSHA PEL: CL 5 mg(Mn)/m³
ACGIH TLV: TWA 5 mg(Mn)/m³

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