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Cas Database |
| Name |
Methyl D-alaninate hydrochloride |
EINECS | 238-258-3 |
| CAS No. | 14316-06-4 | Density | 1.01 g/cm3 |
| PSA | 40.54000 | LogP | 0.43460 |
| Solubility | Soluble in Water 100 mg/ml. | Melting Point |
108-110 °C(lit.) |
| Formula | C4H9NO2.HCl | Boiling Point | 101.5 °C at 760 mmHg |
| Molecular Weight | 139.582 | Flash Point | N/A |
| Transport Information | N/A | Appearance | White crystalline powder |
| Safety | 24/25 | Risk Codes | N/A |
| Molecular Structure |
|
Hazard Symbols |
 Xi
|
| Synonyms |
Alanine,methyl ester, hydrochloride, D- (8CI);D-Alanine, methyl ester, hydrochloride(9CI);(R)-2-Aminopropionic acid methyl ester hydrochloride;(R)-Alanine methylester hydrochloride;NSC 523192;H-D-Ala-OMe·HCl; |
Article Data | 28 |
Methyl D-alaninate hydrochloride Synthetic route
| Conditions | Yield |
|---|---|
| With thionyl chloride at 20℃; for 2h; | 99% |
| With thionyl chloride for 8h; Heating; | 97% |
| With thionyl chloride | 95% |
- 912290-10-9
methyl N-p-dimethylaminobenzylidenealaninate
A
- 2491-20-5
L-alanine methyl ester hydrochloride
B
- 14316-06-4
D-alanine methyl ester hydrochloride
| Conditions | Yield |
|---|---|
| With (-)-O,O′-di-pivaloyl-L-tartaric acid; lithium diisopropyl amide Yield given. Yields of byproduct given. Title compound not separated from byproducts; |
| Conditions | Yield |
|---|---|
| Stage #1: D-Alanine With thionyl chloride Stage #2: methyl iodide |
- 338-69-2
D-Alanine
- 14316-06-4
D-alanine methyl ester hydrochloride
| Conditions | Yield |
|---|---|
| With thionyl chloride In methanol |
| Conditions | Yield |
|---|---|
| With hydrogenchloride at 20℃; |
| Conditions | Yield |
|---|---|
| In dichloromethane at 25℃; Equilibrium constant; |
- 13515-97-4
methyl 2-aminopropanoate monohydrochloride
A
- 2491-20-5
L-alanine methyl ester hydrochloride
B
- 14316-06-4
D-alanine methyl ester hydrochloride
| Conditions | Yield |
|---|---|
| With chiral stationary phase including isopropyl-functionalized CF6 In methanol; acetic acid; triethylamine; acetonitrile at 20℃; Purification / work up; |
- 14316-06-4
D-alanine methyl ester hydrochloride
- 189060-51-3
(3R,5S)-7-chloro-5-(2,3-dimethoxyphenyl)-1-(3-hydroxy-2,2-dimethylpropyl)-2-oxo-1,2,3,5-tetrahydro-4,1-benzoxazepine-3-acetic acid
- 383662-15-5
methyl N-[[(3R,5S)-7-chloro-5-(2,3-dimethoxyphenyl)-1-(3-hydroxy-2,2-dimethylpropyl)-2-oxo-1,2,3,5-tetrahydro-4,1-benzoxazepin-3-yl]acetyl]-D-alaninate
| Conditions | Yield |
|---|---|
| With diethylphosphoryl cyanide; triethylamine In N,N-dimethyl-formamide at 20℃; for 0.5h; | 100% |
- 14316-06-4
D-alanine methyl ester hydrochloride
- 19430-76-3
p-bromophenyl phosphorodichloridate
| Conditions | Yield |
|---|---|
| With triethylamine In dichloromethane at -70 - 20℃; | 100% |
- 1352083-27-2
3-cyclohexyl-2-(pyridin-2-yl)-2H-indazole-6-carboxylic acid
- 14316-06-4
D-alanine methyl ester hydrochloride
- 1352083-28-3
methyl N-{[3-cyclohexyl-2-(pyridin-2-yl)-2H-indazol-6-yl]carbonyl}-D-alaninate
| Conditions | Yield |
|---|---|
| With N-ethyl-N,N-diisopropylamine; HATU In N,N-dimethyl-formamide for 17h; | 100% |
Methyl D-alaninate hydrochloride Chemical Properties
IUPAC Name:methyl (2R)-2-aminopropanoate hydrochloride
Molecular Formula:C4H10ClNO2
Molecular Weight:139.5807 g/mol
Melting Point:108-110 °C(lit.)
alpha:-8°(c=1.6, MeOH)
storage temp.:2-8°C
CAS DataBase Reference:14316-06-4(CAS DataBase Reference)
Synonyms of D-ALANINE METHYL ESTER HCL(14316-06-4):
METHYL D-ALANINATE HYDROCHLORIDE;H-D-ALA-OME HCL;D-2-AMINOPROPIONIC ACID METHYL ESTER HYDROCHLORIDE;D-ALA METHYL ESTER HCL;D-ALANINE METHYL ESTER HCL;D-ALANINE METHYL ESTER HYDROCHLORIDE;D-ALANINE METHYL ESTER HYDROCHLORIDE SALT;D-ALANINE-OME HCL
Categories of D-ALANINE METHYL ESTER HCL(14316-06-4):
Amino Acids Derivatives;Amino Acids;Alanine [Ala, A];Amino Acids and Derivatives;Amino Acid Methyl Esters;Amino Acids (C-Protected);Biochemistry;Amino hydrochloride;Alanine;Amino Acid Derivatives;Peptide Synthesis
Methyl D-alaninate hydrochloride Uses
Methyl D-alaninate hydrochloride Safety Profile
Hazard Codes:Xi
WGK Germany:3
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