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Molybdenum disulfide

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Name

Molybdenum disulfide

EINECS 215-263-9
CAS No. 1317-33-5 Density 5.06 g/mL at 25 °C(lit.)
PSA 64.18000 LogP 1.29640
Solubility N/A Melting Point 2375 °C
Formula MoS2 Boiling Point 450oC, sublimes
Molecular Weight 223.946 Flash Point N/A
Transport Information N/A Appearance dark grey or black powder
Safety 22-24/25 Risk Codes N/A
Molecular Structure Molecular Structure of 1317-33-5 (Molybdenum disulfide (hexagonal)) Hazard Symbols N/A
Synonyms

A Powder;C.I. Pigment Black 34;DAG 325;DMI 7;LM 13;LM 13 (lubricant);Liqui-Moly LM 2;M 5;M 5 (lubricant);MD 40 (lubricant);MVCh 1;Moly Powder B;Moly Powder C;Moly PowderPB;Moly Powder PS;Molybdenum bisulfide;Molybdenum sulphide (MoS2);Molycolloid CF 626;Molyform 15;Molyka R-L3;Molykote;Molykote Z;Molysulfide;Mopol M;Motimol;Nichimoly C;Pigment Black 34;Solvest390A;T-Powder;

 

Molybdenum disulfide Chemical Properties


IUPAC Name: Bis(sulfanylidene)molybdenum
Canonical SMILES: S=[Mo]=S
InChI: InChI=1S/Mo.2S
InChIKey: CWQXQMHSOZUFJS-UHFFFAOYSA-N
Molecular formula: MoS2
Molar mass: 160.07 g/mol
Density: 5.06 g/cm3
Appearance: black solid
Melting point: 1185 °C 
EINECS: 215-263-9
Product Categories: Inorganics 
Stability: Stable. Incompatible with oxidizing agents, acids. 
Appearance: dark grey or black powder
Classification Code of Molybdenum disulfide (CAS NO.1317-33-5): Mutation data

Molybdenum disulfide Uses

 Molybdenum disulfide is often a component of blends and composites where low friction is sought. A variety of oils and greases are used, because they retain their lubricity even in cases of almost complete oil loss, thus finding a use in critical applications such as aircraft engines. MoS2 is often used in two-stroke engines; e.g., motorcycle engines. It is also used in CV and universal joints. During the Vietnam War, the molybdenum disulfide product "Dri-Slide" was used to lubricate weapons, although it was supplied from private sources, not the military. MoS2-coatings allow bullets easier passage through the rifle barrel causing less barrel fouling allowing the barrel to retain ballistic accuracy much longer.

Molybdenum disulfide Production

Molybdenite ore is processed by flotation to give relatively pure Molybdenum disulfide(1317-33-5), the main contaminant being carbon. Molybdenum disulfide(1317-33-5) also arises by the thermal treatment of virtually all molybdenum compounds with hydrogen sulfide. Molybdenite is the principal ore from which molybdenum metal is extracted

Molybdenum disulfide Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LC50 inhalation > 2820mg/m3/4H (2820mg/m3) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES National Technical Information Service. Vol. OTS0001265-2,
rat LD oral > 2gm/kg (2000mg/kg) SKIN AND APPENDAGES (SKIN): HAIR: OTHER National Technical Information Service. Vol. OTS0001265-2,
rat LD skin > 2gm/kg (2000mg/kg) SKIN AND APPENDAGES (SKIN): "DERMATITIS, OTHER: AFTER SYSTEMIC EXPOSURE" National Technical Information Service. Vol. OTS0001265-2,

Molybdenum disulfide Consensus Reports

Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Molybdenum disulfide Safety Profile

Mixtures with potassium nitrate are explosive. Violent reaction with H2O2. When heated to decomposition it emits toxic fumes of SOx and Mo. 
Safety Statements: 22-24/25 
S22:Do not breathe dust. 
S24/25:Avoid contact with skin and eyes.
RTECS: QA4697000

Molybdenum disulfide Standards and Recommendations

OSHA PEL: TWA 5 mg(Mo)/m3
ACGIH TLV: TWA Soluble Compounds: TWA 0.5 mg(Mo)/m3 Confirmed Animal Carcinogen with Unknown Relevance to Humans

Molybdenum disulfide Specification

  Molybdenum disulfide (CAS NO.1317-33-5), its Synonyms are Molybdenum disulfide ; Molybdenum sulfide (MoS2) ; Molybdenum(IV) sulfide ; Molycolloid CF 626 ; Molyke R ; Molykote ; Molykote Microsize Powder ; Molykote Z ; Molysulfide ; Mopol M ; Mopol S ; Motimol ; Natural molybdenite ; Nichimoly C ; Pigment Black 34 ; Solvest 390A ; Sumipowder PA ; T-Powder ; C.I. 77770 ; C.I. Pigment Black 34 ; DAG 206 ; DAG 325 ; DAG-V 657 .

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