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Name	Phenethyl chloride	EINECS	210-725-6
CAS No.	622-24-2	Density	1.052 g/cm³
PSA	0.00000	LogP	2.46790
Solubility	0.1 g/L (20 °C) in water	Melting Point	-60 °C
Formula	C₈H₉Cl	Boiling Point	198.2 °C at 760 mmHg
Molecular Weight	140.612	Flash Point	66.7 °C
Transport Information	N/A	Appearance	clear liquid
Safety	23-24/25-37/39-26	Risk Codes	36/37/38
Molecular Structure		Hazard Symbols	Xi
Synonyms	Benzene, (b-chloroethyl)- (3CI);(2-Chloroethyl)benzene;(b-Chloroethyl)benzene;1-Chloro-2-phenylethane;2-Phenyl-1-chloroethane;2-Phenylethyl chloride;NSC 27886;Phenylethyl chloride;b-Phenethyl chloride;b-Phenylethyl chloride;	Article Data	140

Phenethyl chloride Synthetic route

: 60-12-8
2-phenylethanol

: 622-24-2
2-phenylethyl chloride

Conditions

Conditions	Yield
With trichloroacetamide; triphenylphosphine In dichloromethane at 30℃; for 0.25h;	99%
Stage #1: 2-phenylethanol With N,N-dimethylthiourea In dichloromethane at 20℃; Stage #2: With N-chloro-succinimide In dichloromethane at 20℃; for 1h; Irradiation;	98%
With 1,3,5-trichloro-2,4,6-triazine; N,N-dimethyl-formamide In dichloromethane at 25℃; for 0.25h;	97%

: o-(N-methylcarbamoyl)phenyl 2-phenylethyl sulphoxide

A: 2527-66-4
2-methyl-1,2-benzisothiazole-3(2H)-one

B: 622-24-2
2-phenylethyl chloride

Conditions

Conditions	Yield
With thionyl chloride In dichloromethane for 1h; Heating;	A 99% B 97%

: 20020-27-3
2-phenylethyl mesylate

: 622-24-2
2-phenylethyl chloride

Conditions

Conditions	Yield
With 1-butyl-3-methylimidazolium chloride at 50℃; for 1h; Inert atmosphere; Green chemistry;	98%

: 36794-46-4
diphenethyl-1,1 trimethylene-4,4' bipiperidine

: 622-24-2
2-phenylethyl chloride

Conditions

Conditions	Yield
With phenyl chloroformate In neat (no solvent) Heating;	93%

: 60-12-8
2-phenylethanol

: 2570-00-5
3,3-dichloro-1,2-diphenylcyclopropene

A: 622-24-2
2-phenylethyl chloride

B: 886-38-4
diphenylcyclopropenone

Conditions

Conditions	Yield
In dichloromethane at 23℃; for 0.25h; Mechanism; Solvent; Inert atmosphere;	A 89% B n/a
In dichloromethane at 23℃; for 0.25h;

: 60-12-8
2-phenylethanol

: 98-07-7
Benzotrichlorid

A: 98-87-3
benzylidene dichloride

B: 622-24-2
2-phenylethyl chloride

Conditions

Conditions	Yield
With TOP; phenylsilane In neat (no solvent) at 100℃; for 24h; Appel Halogenation; Inert atmosphere;	A n/a B 88%

: 32327-70-1
1-chloro-4-(2-chloroethyl)benzene

: 622-24-2
2-phenylethyl chloride

Conditions

Conditions	Yield
With palladium on activated charcoal; formic acid; N,N-dimethyl-formamide for 5h; Heating;	85%

: 122-78-1
phenylacetaldehyde

: 622-24-2
2-phenylethyl chloride

Conditions

Conditions	Yield
With dichloromethylsilane; iron(III) chloride In 1,2-dimethoxyethane for 4h; Heating;	85%

: 532-27-4
1-chloroacetophenone

: 622-24-2
2-phenylethyl chloride

Conditions

Conditions	Yield
With titanium tetrachloride In 1,2-dichloro-ethane for 3h; Reflux;	85%

: 60-12-8
2-phenylethanol

: 98-88-4
benzoyl chloride

A: 94-47-3
2-Phenylethyl benzoate

B: 622-24-2
2-phenylethyl chloride

Conditions

Conditions	Yield
With 2,3-diethyl-2-cyclopropen-1-one In tert-butyl methyl ether at 40℃; for 15h;	A n/a B 83%

Phenethyl chloride Chemical Properties

Product Name: 1-Chloro-2-phenylethane
CAS Registry Number: 622-24-2
IUPAC Name: 1-chloro-2-ethylbenzene
Molecular Weight: 140.61006 [g/mol]
Molecular Formula: C₈H₉Cl
XLogP3: 3.5
Surface Tension: 33.8 dyne/cm
EINECS: 210-725-6
Density: 1.052 g/cm³
Flash Point: 66.7 °C
Melting Point: -60 °C
Refractive index: n20/D 1.53(lit.)
Water Solubility: 0.1 g/L (20 ºC)
Enthalpy of Vaporization: 41.67 kJ/mol
Boiling Point: 198.2 °C at 760 mmHg
Vapour Pressure: 0.512 mmHg at 25°C
Product Categories: Benzene derivates
Following is the molecular structure of 1-Chloro-2-phenylethane (CAS NO.622-24-2) is:

Phenethyl chloride Safety Profile

Safty information about 1-Chloro-2-phenylethane (CAS NO.622-24-2) is:
Hazard Codes:
Irritant Xi
Risk Statements:
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements:
S23:Do not breathe vapour.
S24/25:Avoid contact with skin and eyes.
S37/39:Wear suitable gloves and eye/face protection.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
WGK Germany: 3
HS Code: 29036990

Phenethyl chloride Specification

1-Chloro-2-phenylethane (CAS NO.622-24-2) is a clear, colorless liquid.
First Aid Measures about it:
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Get medical aid. Wash mouth out with water.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Handling and Storage about it:
Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage: Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container.

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