[(E)-N'-((2-oxy-3-methoxybenzylidene)benzoylhydrazone-κ3O,N,O')(4-pyridinecarboxylato-κN)copper(II)]

Base Information

• Chemical Name: [(E)-N'-((2-oxy-3-methoxybenzylidene)benzoylhydrazone-κ3O,N,O')(4-pyridinecarboxylato-κN)copper(II)]
• CAS No.: 1269170-16-2
• Molecular Formula: C₂₁H₁₇CuN₃O₅
• Molecular Weight: 454.929
• Mol file: 1269170-16-2.mol

Synonyms:

Chemical Property of [(E)-N'-((2-oxy-3-methoxybenzylidene)benzoylhydrazone-κ3O,N,O')(4-pyridinecarboxylato-κN)copper(II)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(E)-N'-((2-oxy-3-methoxybenzylidene)benzoylhydrazone-κ3O,N,O')(4-pyridinecarboxylato-κN)copper(II)]

There total 3 articles about [(E)-N'-((2-oxy-3-methoxybenzylidene)benzoylhydrazone-κ3O,N,O')(4-pyridinecarboxylato-κN)copper(II)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[(E)-N'-((2-oxy-3-methoxybenzylidene)benzoylhydrazido-κ3O,N,O')(4-pyridinecarboxylic acid-κN)copper(II)] (1269170-16-2) → [(E)-N'-((2-oxy-3-methoxybenzylidene)benzoylhydrazone-κ3O,N,O')(4-pyridinecarboxylato-κN)copper(II)] (1269170-16-2)

Guidance literature:

In acetonitrile; for 2 wk;

DOI:10.1039/c0dt00371a

Reference yield:

[(E)-N'-((2-oxy-3-methoxybenzylidene)benzoylhydrazone-κ3O,N,O')(4-pyridinecarboxylato-κN)copper(II)] monohydrate monoethanol → [(E)-N'-((2-oxy-3-methoxybenzylidene)benzoylhydrazido-κ3O,N,O')(4-pyridinecarboxylic acid-κN)copper(II)] (1269170-16-2)

Guidance literature:

In acetonitrile; for 2 wk;

DOI:10.1039/c0dt00371a

Reference yield:

pyridine-4-carboxylic acid (55-22-1) + ethanol (64-17-5) + copper(II) acetate monohydrate (6046-93-1) + benzoic acid hydrazide (613-94-5) + 3-methoxy-2-hydroxybenzaldehyde (148-53-8) → [(E)-N'-((2-oxy-3-methoxybenzylidene)benzoylhydrazido-κ3O,N,O')(4-pyridinecarboxylic acid-κN)copper(II)] (1269170-16-2) + [(E)-N'-((2-oxy-3-methoxybenzylidene)benzoylhydrazone-κ3O,N,O')(4-pyridinecarboxylato-κN)copper(II)] monohydrate monoethanol

Guidance literature:

In ethanol; byproducts: H2O; benzhydrazide, CH3OC6H3(OH)CHO, C5H4NCO2H, and Cu salt placed in the main arm of a branched tube, EtOH added carefully to fill the arms, the tube sealed, the Cu salt contg. arm heated at 60°C while the other arm kept at ambient temp. for 2 wk; filtered off, washed (EtOH), air-dried, sepd. manually; elem. anal.;

DOI:10.1039/c0dt00371a

upstream raw materials:

pyridine-4-carboxylic acid

ethanol

copper(II) acetate monohydrate

benzoic acid hydrazide