(2E)-2,7-Octadiene-1-ol acetate

Base Information

• Chemical Name: (2E)-2,7-Octadiene-1-ol acetate
• CAS No.: 30460-73-2
• Molecular Formula: C10H16O2
• Molecular Weight: 168.236
• Mol file: 30460-73-2.mol

Synonyms:trans-2,7-octadienyl acetate;2E,7-octadien-1-yl acetate;1-acetoxy-2,7-octadiene;(E)-octa-2,7-dien-1-yl acetate;2,7-octadienyl acetate;(E)-2,7-octadienyl acetate;

Chemical Property of (2E)-2,7-Octadiene-1-ol acetate

Chemical Property:

• Boiling Point: 225.0±19.0 °C(Predicted)
• PSA: 26.30000
• Density: 0.905±0.06 g/cm3(Predicted)
• LogP: 2.46200

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (2E)-2,7-Octadiene-1-ol acetate

There total 1 articles about (2E)-2,7-Octadiene-1-ol acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

acetic acid (64-19-7,77671-22-8) + buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) → octa-1,3,7-triene (1002-35-3) + octa-1,7-dien-3-yl acetate (3491-26-7) + (E)-1-acetoxy-2,7-octadiene (30460-73-2)

Guidance literature:

With triethylamine; phosphinated polystyrene-bound Pd⁽⁰⁾; In acetone; at 95 ℃; for 20h; Product distribution; the other catalyst and reaction time, different solvents and reagents; various carboxylic acids and H₂O;

DOI:10.1021/jo00324a029

Reference yield: 67.0%

(E)-1-acetoxy-2,7-octadiene (30460-73-2) → 1,7-Octadiene (3710-30-3)

Guidance literature:

With formic acid; triethylamine; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; tributylphosphine; In tetrahydrofuran; for 2h; Heating;

DOI:10.1055/s-1986-31723

Reference yield: 60.0%

benzyl bromide (100-39-0) + (E)-1-acetoxy-2,7-octadiene (30460-73-2) → 9-phenyl-trans-1,6-nonadiene (88787-20-6)

Guidance literature:

With palladium(II) acetylacetonate; triphenylphosphine; zinc; In tetrahydrofuran; at 60 ℃; for 5h;

upstream raw materials:

acetic acid

buta-1,3-diene

Downstream raw materials:

N,N-bis(2E,7-octadienyl)aniline

9-phenyl-trans-1,6-nonadiene

trans-1-phenyl-2,7-octadiene

N-(2E,7-octadienyl)-N-methyl-α-phenyl(n-propyl)amine

Refernces