Benzenemethanamine, 4-methoxy-N-(phenylmethylene)-

Base Information

• Chemical Name: Benzenemethanamine, 4-methoxy-N-(phenylmethylene)-
• CAS No.: 31490-38-7
• Molecular Formula: C15H15NO
• Molecular Weight: 225.29
• DSSTox Substance ID: DTXSID60450123
• Nikkaji Number: J595.637D,J2.051.746H
• Mol file: 31490-38-7.mol

Synonyms:206768-78-7;(E)-[(4-methoxyphenyl)methyl](phenylmethylidene)amine;Benzenemethanamine, 4-methoxy-N-(phenylmethylene)-;31490-38-7;p-methoxybenzalbenzylamine;SCHEMBL8544003;SCHEMBL10322462;DTXSID60450123;UHERNABOIPEDIY-LFIBNONCSA-N;N-Benzylidene-4-methoxybenzylamine;N-[(E)-Benzylidene]-4-methoxybenzylamine;EN300-6734182;(E)-N-Benzylidene-1-(4-methoxyphenyl)methanamine;(4-methoxy-benzyl)-[1-phenyl-meth-(E)-ylidene]-amine

Chemical Property of Benzenemethanamine, 4-methoxy-N-(phenylmethylene)-

Chemical Property:

• XLogP3: 3.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 225.115364102
• Heavy Atom Count: 17
• Complexity: 225

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)CN=CC2=CC=CC=C2

Technology Process of Benzenemethanamine, 4-methoxy-N-(phenylmethylene)-

There total 31 articles about Benzenemethanamine, 4-methoxy-N-(phenylmethylene)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

benzaldehyde (100-52-7) + 4-methoxy-benzylamine (2393-23-9) → N-(4-methoxybenzyl)benzaldimine (31490-38-7)

Guidance literature:

With magnesium sulfate; In dichloromethane; at 20 ℃; for 12h;

DOI:10.1002/ejoc.200800363

Reference yield: 96.0%

4-methoxy-benzylamine (2393-23-9) + benzyl alcohol (100-51-6,185532-71-2) → N-(4-methoxybenzyl)benzaldimine (31490-38-7)

Guidance literature:

With 5H₂O*4H₃N*4H⁽¹⁺⁾*[CuMo₆O₁₈(OH)6]^(4-); oxygen; In acetonitrile; at 50 ℃; for 12h; under 760.051 Torr;

DOI:10.1002/chem.201703185

Reference yield: 95.1%

benzonitrile (100-47-0) + 4-methoxy-benzylamine (2393-23-9) → N-(4-methoxybenzyl)benzaldimine (31490-38-7)

Guidance literature:

With ammonium hydroxide; hydrogen; In hexane; at 80 ℃; for 12h; under 750.075 Torr; Autoclave; Green chemistry;

DOI:10.1021/acscatal.9b01597

upstream raw materials:

N-(4-methoxylbenzylidene)benzylamine

sodium ethanolate

benzaldehyde

4-methoxy-benzylamine

Downstream raw materials:

N-(4-methoxylbenzylidene)benzylamine

diethyl (((4-methoxybenzyl)amino)(phenyl)methyl)phosphonate

(4-methoxy-benzyl)-(2-methyl-2-nitro-1-phenyl-propyl)-amine

benzaldehyde