N-(4-methoxyphenyl)methanimine

Base Information

• Chemical Name: N-(4-methoxyphenyl)methanimine
• CAS No.: 32328-80-6
• Molecular Formula: C8H9NO
• Molecular Weight: 135.166
• DSSTox Substance ID: DTXSID60451150
• Nikkaji Number: J891.086C
• Wikidata: Q82271027
• Mol file: 32328-80-6.mol

Synonyms:N-(4-methoxyphenyl)methanimine;32328-80-6;Benzenamine, 4-methoxy-N-methylene-;SCHEMBL13185916;DTXSID60451150;AKOS006306470

Chemical Property of N-(4-methoxyphenyl)methanimine

Chemical Property:

• PSA: 21.59000
• LogP: 2.02730
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 135.068413911
• Heavy Atom Count: 10
• Complexity: 106

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)N=C

Technology Process of N-(4-methoxyphenyl)methanimine

There total 3 articles about N-(4-methoxyphenyl)methanimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

formaldehyd (50-00-0,30525-89-4,61233-19-0) + 4-methoxy-aniline (104-94-9) → N-(4-methoxyphenyl)methylenamine (32328-80-6)

Guidance literature:

With 1-ethyl-3-methylimidazolium (S)-2-pyrrolidinecarboxylic acid salt; In dichloromethane; water; at 20 ℃;

DOI:10.1016/j.catcom.2009.12.021

Reference yield:

methanol (67-56-1) + para-methoxynitrobenzene (100-17-4) + carbon monoxide (201230-82-2) → methyl N-(4-methoxyphenyl)carbamate (14803-72-6) + N-(4-methoxyphenyl)methylenamine (32328-80-6)

Guidance literature:

With 1,10-Phenanthroline; Pd(1,10-phenanthroline)2(OTf)2; at 135 ℃; for 2h; under 45003.6 Torr; Yield given;

Reference yield:

1,3,5-tris(4-methoxyphenyl)-1,3,5-triazinane (32752-37-7) → N-(4-methoxyphenyl)methylenamine (32328-80-6)

Guidance literature:

at 300 ℃; Yield given;

upstream raw materials:

1,3,5-tris(4-methoxyphenyl)-1,3,5-triazinane

methanol

para-methoxynitrobenzene

carbon monoxide

Downstream raw materials:

N-methyl-N-(4-methoxyphenyl)amine

C₁₄H₁₇NO₂

C₁₅H₁₉NO₂

C₁₄H₁₇NO₂