Germane, tris(2,4,6-trimethylphenyl)-

Base Information

• Chemical Name: Germane, tris(2,4,6-trimethylphenyl)-
• CAS No.: 3265-03-0
• Molecular Formula: C27H34Ge
• Molecular Weight: 431.157
• Mol file: 3265-03-0.mol

Synonyms:

Chemical Property of Germane, tris(2,4,6-trimethylphenyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Germane, tris(2,4,6-trimethylphenyl)-

There total 17 articles about Germane, tris(2,4,6-trimethylphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

trimesitylgermyllithium (120154-50-9) + 2,4,6-tri-tert-butyl-1-nitrosobenzene (24973-59-9) → trimesitylgermane (3265-03-0) + chlorotri(2,4,6-trimethylphenyl)germane (62120-68-7) + triphenylgermane (2816-43-5)

Guidance literature:

With hydrogenchloride; In tetrahydrofuran; diethyl ether; inert atmosphere; addn. of org. compd. soln. (THF) to soln. of Ge-compd. (THF/Et2O) at -20°C, keeping at same temp. for 30 min, at room temp. for 1 h, soln. hydrolysis; twice extn. (Et2O), drying (Na2SO4), soln. concn. (reduced pressure); (1)H-NMR and ESR spectroscopy;

DOI:10.1016/0022-328X(93)80008-Y

Reference yield: 64.0%

trimesitylgermyllithium (120154-50-9) + 2,3,4,5-tetraphenylcyclopenta-2,4-dienone (479-33-4) → trimesitylgermane (3265-03-0) + chlorotri(2,4,6-trimethylphenyl)germane (62120-68-7)

Guidance literature:

With hydrogenchloride; In diethyl ether; inert atmosphere; treatment of reaction mixt. with HCl; soln. drying (Na2SO4), concn. (reduced pressure); (1)H-NMR spectroscopy;

DOI:10.1016/0022-328X(93)80008-Y

Reference yield: 63.0%

chlorotri(2,4,6-trimethylphenyl)germane (62120-68-7) + Dimethyldisulphide (624-92-0) + 1,1',3,3'-tetramethyl-2,2'-biimidazolidinylidene (1911-01-9) → trimesitylgermane (3265-03-0) + trimesityl(methylthio)germane (129016-30-4) + chlorotriphenylgermane (1626-24-0)

Guidance literature:

In benzene; byproducts: C2H4N2Me2CCl2; Irradiation (UV/VIS); (N2 or Ar), dry solvents; irradn. (2537 ?) of an excess of MeSSMe, E.R.O. and Ge-compd. in C6H6 at 20°C (2 h);;

upstream raw materials:

lithium aluminium tetrahydride

chlorotri(2,4,6-trimethylphenyl)germane

trimesitylgermyllithium

α,α'-dibromo-o-xylene

Downstream raw materials:

Methyl-tris-(2,4,6-trimethyl-phenyl)-germane

{C₆H₂(CH₃)3}3Ge₂(C₂H₅)3

chlorotri(2,4,6-trimethylphenyl)germane

trimesityl(methylthio)germane