methyl 4-methyl-1-naphthoate

Base Information

• Chemical Name: methyl 4-methyl-1-naphthoate
• CAS No.: 35615-98-6
• Molecular Formula: C₁₃H₁₂O₂
• Molecular Weight: 200.237
• Hs Code.: 2916399090
• Mol file: 35615-98-6.mol

Synonyms:4-carbomethoxy-1-methylnaphthalene;1-Naphthalenecarboxylic acid, 4-methyl-, methyl ester;4-methyl-1-naphthalenecarboxylic acid,methyl ester;4-methyl-naphthalene-1-carboxylic acid methyl ester;methyl ester of 4-methyl-1-naphthalenecarboxylic acid;METHYL 4-METHYL-1-NAPHTHOATE;

Chemical Property of methyl 4-methyl-1-naphthoate

Chemical Property:

• Boiling Point: 323.7±11.0 °C(Predicted)
• PSA: 26.30000
• Density: 1.126±0.06 g/cm3(Predicted)
• LogP: 2.93480

Purity/Quality:

99% ^*data from raw suppliers

Methyl4-methyl-1-naphthoate 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of methyl 4-methyl-1-naphthoate

There total 9 articles about methyl 4-methyl-1-naphthoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

4-Methyl-1-naphthoic acid (4488-40-8) + methyl iodide (74-88-4) → methyl 4-methyl-1-naphthalenecarboxylate (35615-98-6)

Guidance literature:

4-Methyl-1-naphthoic acid; With potassium carbonate; In N,N-dimethyl-formamide; at 20 ℃; for 0.5h;

methyl iodide; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 3h;

Reference yield: 97.0%

methanol (67-56-1) + 4-Methyl-1-naphthoic acid (4488-40-8) → methyl 4-methyl-1-naphthalenecarboxylate (35615-98-6)

Guidance literature:

With thionyl chloride; at 60 ℃;

Reference yield:

methyl 4-bromomethylnaphthalene-1-carboxylate (2417-75-6) → methyl 4-methyl-1-naphthalenecarboxylate (35615-98-6)

Guidance literature:

With potassium phtalimide; In DMF (N,N-dimethyl-formamide); at 20 ℃; for 12h;

upstream raw materials:

diazomethane

4-Methyl-1-naphthoic acid

carbon dioxide

1-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-4-methyl naphtalene

Downstream raw materials:

4-formylnaphthalene-1-carboxylic acid

(Z)-4-(5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydroisoxazol-3-yl)-N-(2-(isopropoxyimino)ethyl)-1-naphthamide

(E)-4-(5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydroisoxazol-3-yl)-N-(2-(isopropoxyimino)ethyl)-1-naphthamide

4-(5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydroisoxazol-3-yl)-N-(3,3,3-trifluoro-2-hydroxypropyl)-1-naphthamide