Piperidine, 1-(2,4-dinitro-1-naphthalenyl)-

Base Information

• Chemical Name: Piperidine, 1-(2,4-dinitro-1-naphthalenyl)-
• CAS No.: 52422-07-8
• Molecular Formula: C15H15N3O4
• Molecular Weight: 301.302
• DSSTox Substance ID: DTXSID00389362
• Nikkaji Number: J259.238J
• Wikidata: Q82185090
• Mol file: 52422-07-8.mol

Synonyms:Piperidine, 1-(2,4-dinitro-1-naphthalenyl)-;52422-07-8;1-(2,4-Dinitro-naphthalen-1-yl)-piperidine;Oprea1_130757;DTXSID00389362;1-Piperidino-2,4-dinitronaphthalene;AKOS000520975

Chemical Property of Piperidine, 1-(2,4-dinitro-1-naphthalenyl)-

Chemical Property:

• XLogP3: 3.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 1
• Exact Mass: 301.10625597
• Heavy Atom Count: 22
• Complexity: 428

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCN(CC1)C2=C(C=C(C3=CC=CC=C32)[N+](=O)[O-])[N+](=O)[O-]

Technology Process of Piperidine, 1-(2,4-dinitro-1-naphthalenyl)-

There total 7 articles about Piperidine, 1-(2,4-dinitro-1-naphthalenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 14.0%

piperidine (110-89-4) + 1-dimethylamino-2,4-dinitronaphthalene (39139-79-2) → 2,4-dinitro-1-(1-piperidyl)naphthalene (52422-07-8) + dimethyl amine (124-40-3)

Guidance literature:

at 80 ℃; for 24h;

DOI:10.1039/c39880000698

Reference yield: 6.0%

piperidine (110-89-4) + 1-(pyrrolidinyl)-2,4-dinitronaphthalene (78521-30-9) → pyrrolidine (123-75-1) + 2,4-dinitro-1-(1-piperidyl)naphthalene (52422-07-8)

Guidance literature:

at 50 ℃; for 24h;

DOI:10.1039/c39880000698

Reference yield:

C17H20N3O5(1-) (53359-90-3) → ethanol (64-17-5) + 2,4-dinitro-1-(1-piperidyl)naphthalene (52422-07-8)

Guidance literature:

In dimethyl sulfoxide; at 25 ℃; Rate constant; kinetic of reactions of cyclic secondary amines (pyrrolidine, piperidine) with 2,4-dinitro-1-naphthyl ethyl ether in DMSO; stage II kinetics (with piperidine); difference between the piperidine and pyrrolidine systems;

DOI:10.1021/ja00406a032

upstream raw materials:

piperidine

ethyl ether of 2,4-dinitro-1-naphthol

phenyl 2,4-dinitronaphthyl sulfide

C₁₇H₂₀N₃O₅^(1-)

Downstream raw materials:

piperidine

1-(Methylamino)-2,4-dinitronaphthalene