1-(pyrrolidinyl)-2,4-dinitronaphthalene

Base Information

• Chemical Name: 1-(pyrrolidinyl)-2,4-dinitronaphthalene
• CAS No.: 78521-30-9
• Molecular Formula: C₁₄H₁₃N₃O₄
• Molecular Weight: 287.275
• Mol file: 78521-30-9.mol

Synonyms:1-(pyrrolidinyl)-2,4-dinitronaphthalene

Chemical Property of 1-(pyrrolidinyl)-2,4-dinitronaphthalene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-(pyrrolidinyl)-2,4-dinitronaphthalene

There total 6 articles about 1-(pyrrolidinyl)-2,4-dinitronaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

pyrrolidine (123-75-1) + 1-dimethylamino-2,4-dinitronaphthalene (39139-79-2) → 1-(pyrrolidinyl)-2,4-dinitronaphthalene (78521-30-9) + dimethyl amine (124-40-3)

Guidance literature:

at 80 ℃; for 0.5h;

DOI:10.1039/c39880000698

Reference yield:

C18H21N4O4(1-) → pyrrolidine (123-75-1) + 1-(pyrrolidinyl)-2,4-dinitronaphthalene (78521-30-9)

Guidance literature:

With pyrrolidine hydrochloride; In dimethyl sulfoxide; at 25 ℃; Equilibrium constant; Mechanism; reversible reactions of amines with the corresponding N-(2,4-dinitro-1-naphthylamines); difference between pyrrolidine and piperidine systems;

DOI:10.1021/ja00406a033

Reference yield:

C16H18N3O5(1-) → ethanol (64-17-5) + 1-(pyrrolidinyl)-2,4-dinitronaphthalene (78521-30-9)

Guidance literature:

In dimethyl sulfoxide; at 25 ℃; Rate constant; kinetic of reactions of cyclic secondary amines (pyrrolidine, piperidine) with 2,4-dinitro-1-naphthyl ethyl ether in DMSO; stage II kinetics (with pyrrollidine); difference between the pyrrolidine and piperidine systems;

DOI:10.1021/ja00406a032

upstream raw materials:

pyrrolidine

ethyl ether of 2,4-dinitro-1-naphthol

phenyl 2,4-dinitronaphthyl sulfide

1-dimethylamino-2,4-dinitronaphthalene

Downstream raw materials:

pyrrolidine

2,4-dinitro-1-(1-piperidyl)naphthalene

1-(Methylamino)-2,4-dinitronaphthalene

Refernces

• 1、 Fujinuma, Hajime,Hosokawa, Masaru,Suzuki, Tohru,Sato, Mitsuo,Sekiguchi, Shizen. "Sopped-Flow Kinetics of 1-Ethoxy-2,4-dinitronaphthalene with Pyrrolidine and Piperidine in Dimethyl Sulfoxide Solution". . p. 1969 - 1975. Retrieved 2007/10/02.
• 2、 Bunnett, Joseph F.,Sekiguchi, Shizen,Smith, Lewis A.. "Kinetics of Reactions of Cyclic Secondary Amines with 2,4-Dinitro-1-naphthyl Ethyl Ether in Dimethyl Sulfoxide Solution. Spectacular Difference between the Behavior of Pyrrolidine and Piperidine". . p. 4865 - 4871. Retrieved 2007/10/02.