Triphenyl{bis[(trifluoroacetyl)oxy]}-lambda~5~-stibane

Base Information

Chemical Name:Triphenyl{bis[(trifluoroacetyl)oxy]}-lambda~5~-stibane
CAS No.:36971-66-1
Molecular Formula:C22H15 F6 O4 Sb
Molecular Weight:579.099
Hs Code.:
DSSTox Substance ID:DTXSID80586791
NSC Number:171098
Wikidata:Q82478995
Mol file:36971-66-1.mol

Synonyms:36971-66-1;Triphenyl{bis[(trifluoroacetyl)oxy]}-lambda~5~-stibane;DTXSID80586791;NSC171098;NSC-171098;triphenyl-antimony bis(trifluoroacetate);Antimony, triphenylbis[(2,2,2-trifluoroacetyl)oxy]-

Suppliers and Price of Triphenyl{bis[(trifluoroacetyl)oxy]}-lambda~5~-stibane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of Triphenyl{bis[(trifluoroacetyl)oxy]}-lambda~5~-stibane

Chemical Property:

Boiling Point:°Cat760mmHg
Flash Point:°C
Density:g/cm³
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:10
Rotatable Bond Count:7
Exact Mass:577.99126
Heavy Atom Count:33
Complexity:624

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)[Sb](C2=CC=CC=C2)(C3=CC=CC=C3)(OC(=O)C(F)(F)F)OC(=O)C(F)(F)F

Technology Process of Triphenyl{bis[(trifluoroacetyl)oxy]}-lambda~5~-stibane

There total 3 articles about Triphenyl{bis[(trifluoroacetyl)oxy]}-lambda~5~-stibane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 2923-18-4
sodium 2,2,2-trifluoroacetate

: 603-36-1
triphenylantimony

: 36971-66-1
triphenylantimony bis(trifluoroacetate)

Guidance literature:: In methanol; acetonitrile; Electrolysis; N2 atmosphere, ambient temp.; constant current electrolysis (Pt plate and wire electrodes); extraction (ethyl acetate), washing of extracts (water, brine), drying (MgSO4), solvent removal, recrystn. (ethanol);
DOI:10.1016/S0013-4686(97)85470-9

Reference yield: 62.0%

: 603-36-1
triphenylantimony

: 76-05-1
trifluoroacetic acid

: 7440-36-0
antimony

: 36971-66-1
triphenylantimony bis(trifluoroacetate)

Guidance literature:: In benzene; reflux for 2 h;

Reference yield:

: 603-36-1
triphenylantimony

: 76-05-1
trifluoroacetic acid

: 36971-66-1
triphenylantimony bis(trifluoroacetate)

Guidance literature:: With tert.-butylhydroperoxide; In diethyl ether; byproducts: t-BuOH, H2O; t-BuOOH was added dropwise to stirred cold (5-10°C) soln. of Sb-compound and acid in Et2O, kept in the dark for 24 h at room temp.; solvent was distilled off under reduced pressure, recrystd. from CHCl3/hexane;
DOI:10.1016/S0022-328X(02)02179-4