trans-Methyl 2-phenylcyclopropane-1-carboxylate

Base Information

Chemical Name:trans-Methyl 2-phenylcyclopropane-1-carboxylate
CAS No.:5861-31-4
Molecular Formula:C₁₁H₁₂O₂
Molecular Weight:176.215
Hs Code.:
European Community (EC) Number:829-934-4
Nikkaji Number:J305.241I
Wikidata:Q76303461
Mol file:5861-31-4.mol

Synonyms:5861-31-4;trans-Methyl 2-phenylcyclopropane-1-carboxylate;Methyl (1R,2R)-2-Phenylcyclopropanecarboxylate;ghl.PD_Mitscher_leg0.955;methyl (1R,2R)-2-phenylcyclopropane-1-carboxylate;SCHEMBL1223722;AC8629;AKOS034811491;methyltrans-2-phenyl-1-cyclopropanecarboxylate;EN300-173049;rac-methyl (1R,2R)-2-phenylcyclopropane-1-carboxylate;Z2327124590;1beta-Phenyl-2alpha-cyclopropanecarboxylic acid methyl ester

Suppliers and Price of trans-Methyl 2-phenylcyclopropane-1-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of trans-Methyl 2-phenylcyclopropane-1-carboxylate

Chemical Property:

Boiling Point:90 °C(Press: 25 Torr)
Density:1.136±0.06 g/cm3(Predicted)
XLogP3:2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:176.083729621
Heavy Atom Count:13
Complexity:194

Purity/Quality:: 95% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1CC1C2=CC=CC=C2
Isomeric SMILES:COC(=O)[C@@H]1C[C@H]1C2=CC=CC=C2

Technology Process of trans-Methyl 2-phenylcyclopropane-1-carboxylate

There total 96 articles about trans-Methyl 2-phenylcyclopropane-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1205000-67-4
(+)-trans-2,2-dibromo-3-phenylcyclopropanecarboxylic acid methyl ester

: 5682-61-1,5861-31-4,10488-03-6,16205-72-4,20030-70-0,67528-62-5,67528-63-6,67528-69-2,67528-70-5
(1R,2R)-2-phenylcyclopropanecarboxylic acid methyl ester

Guidance literature:: With tri-n-butyl-tin hydride; In benzene; at 20 - 55 ℃; Inert atmosphere;
DOI:10.1016/j.tet.2009.10.077

Reference yield: 97.0%

: 67-56-1
methanol

: 939-90-2
trans-2-phenylcyclopropane-1-carboxylic acid

: 5861-31-4,16205-72-4
methyl trans-2-phenylcyclopropanecarboxylate

Guidance literature:: With thionyl chloride; Reflux; Inert atmosphere;
DOI:10.1055/s-0030-1258084

Reference yield: 95.0%

: 80-11-5
N-methyl-N-nitrosotoluene-p-sulfonamide

: 103-26-4,1754-62-7
methyl cinnamate

: 5861-31-4,16205-72-4
methyl trans-2-phenylcyclopropanecarboxylate

Guidance literature:: N-methyl-N-nitrosotoluene-p-sulfonamide; With potassium hydroxide; In methanol; water; N,N-dimethyl-formamide; Flow reactor;

methyl cinnamate; With palladium diacetate; In tetrahydrofuran; methanol; diethyl ether; water; N,N-dimethyl-formamide; at 0 ℃;
DOI:10.1021/acs.joc.6b01190