Methyl(phenyl)(trimethylsilyl)phosphane

Base Information

• Chemical Name: Methyl(phenyl)(trimethylsilyl)phosphane
• CAS No.: 59877-21-3
• Molecular Formula: C10H17PSi
• Molecular Weight: 196.304
• DSSTox Substance ID: DTXSID10544081
• Nikkaji Number: J3.307.994J
• Mol file: 59877-21-3.mol

Synonyms:Methyl(phenyl)(trimethylsilyl)phosphane;59877-21-3;SCHEMBL14497195;DTXSID10544081;methyl(phenyl)(trimethylsilyl)phosphine

Chemical Property of Methyl(phenyl)(trimethylsilyl)phosphane

Chemical Property:

• PSA: 13.59000
• LogP: 3.25850
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 196.083714074
• Heavy Atom Count: 12
• Complexity: 133

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)P(C)C1=CC=CC=C1

Technology Process of Methyl(phenyl)(trimethylsilyl)phosphane

There total 4 articles about Methyl(phenyl)(trimethylsilyl)phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

chloro-trimethyl-silane (75-77-4) + methylphenylphosphine (6372-48-1) → methyl(phenyl)(trimethylsilyl)phosphine (59877-21-3)

Guidance literature:

methylphenylphosphine; With n-butyllithium; In tetrahydrofuran; hexane; at 20 ℃; for 1h;

chloro-trimethyl-silane; In tetrahydrofuran; hexane; for 24h;

DOI:10.1515/znb-2000-1010

Reference yield: 85.0%

trimethylsulphonium iodide (2181-42-2) + bis(trimethylsilyl)phenylphosphine (24103-44-4) → methyl(phenyl)(trimethylsilyl)phosphine (59877-21-3)

Guidance literature:

trimethylsulphonium iodide; With n-butyllithium; In tetrahydrofuran; hexane; at -70 ℃; for 0.166667h;

bis(trimethylsilyl)phenylphosphine; In tetrahydrofuran; hexane; at 20 ℃; for 3h;

DOI:10.1023/A:1023353615773

Reference yield:

chloro-trimethyl-silane (75-77-4) + diphenyl(methyl)phosphine (1486-28-8) → methyl(phenyl)(trimethylsilyl)phosphine (59877-21-3)

Guidance literature:

diphenyl(methyl)phosphine; With lithium; In tetrahydrofuran; at 20 ℃; for 24h; Inert atmosphere;

chloro-trimethyl-silane; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1039/b909749j

upstream raw materials:

chloro-trimethyl-silane

methylphenylphosphine

trimethylsulphonium iodide

bis(trimethylsilyl)phenylphosphine

Downstream raw materials:

Methylphenyl(trifluoroacetyl)phosphan

1,2-dimethyl-1,2-diphenyldiphosphine

methyl(phenyl)chlorophosphine

Acetylmethylphenylphosphan