L-gulopyranose

Base Information

• Chemical Name: L-gulopyranose
• CAS No.: 6027-89-0
• Molecular Formula: C6H12O6
• Molecular Weight: 180.158
• Hs Code.: 29400090
• Wikidata: Q27117232
• Metabolomics Workbench ID: 42000
• Mol file: 6027-89-0.mol

Synonyms:L-gulopyranose;L-(+)-Gulose;(3S,4S,5S,6S)-6-(hydroxymethyl)oxane-2,3,4,5-tetrol;L-Gulo-hexose;L(+)-Gulose;L-()-Gulose;SCHEMBL9898186;CHEBI:37704;WQZGKKKJIJFFOK-QRXFDPRISA-N;L-(+)-Gulose, >=98.0% (HPLC);G0239;J-200004;W-203249;Q27117232

Chemical Property of L-gulopyranose

Chemical Property:

• Appearance/Colour: light yellow viscous oil
• Vapor Pressure: 0mmHg at 25°C
• Melting Point: 132 °C
• Refractive Index: 25 ° (C=0.5, H2O)
• Boiling Point: 410.8 °C at 760 mmHg
• PKA: 12.45±0.20(Predicted)
• Flash Point: 202.2 °C
• PSA: 118.22000
• Density: 1.732 g/cm³
• LogP: -3.37880
• Storage Temp.: 2-8°C
• Solubility.: DMSO (Slightly), Methanol (Slightly), Water (Slightly)
• XLogP3: -2.6
• Hydrogen Bond Donor Count: 5
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 1
• Exact Mass: 180.06338810
• Heavy Atom Count: 12
• Complexity: 151

Purity/Quality:

98%, ^*data from raw suppliers

L-Gulose ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 24/25-36/37/39-27-26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C(C1C(C(C(C(O1)O)O)O)O)O
• Isomeric SMILES: C([C@H]1[C@H]([C@@H]([C@@H](C(O1)O)O)O)O)O
• Uses: L-Gulose is an aldohexose sugar. L-Gulose very rarely occurs in nature but has been found in archaea, bacteria and eukaryotes. L-Gulose is not fermentable by yeast. L-Gulose also serves as a direct precursor of L-ascorbic acid in plant cells. L-gulose is a compound useful in organic synthesis.

Technology Process of L-gulopyranose

There total 154 articles about L-gulopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

D-sorbitol (50-70-4) → D-Fructose (57-48-7,18875-34-8) + L-sorbose (87-79-6,18875-34-8) + L-gulose (6027-89-0) + D-glucose (50-99-7)

Guidance literature:

With sulfuric acid; Electrochemical reaction; Inert atmosphere;

DOI:10.1002/cssc.201402880

Reference yield:

D-sorbitol (50-70-4) → formic acid (64-18-6) + D-Fructose (57-48-7,18875-34-8) + L-sorbose (87-79-6,18875-34-8) + L-gulose (6027-89-0) + D-glucose (50-99-7) + gluconic acid (526-95-4)

Guidance literature:

With sulfuric acid; platinum on activated charcoal; Reagent/catalyst; Electrochemical reaction; Inert atmosphere;

DOI:10.1002/cssc.201402880

Reference yield:

D-sorbitol (50-70-4) + water (7732-18-5) → D-Arabinose (10323-20-3) + L-xylose (609-06-3) + L-gulose (6027-89-0) + D-glucose (50-99-7)

Guidance literature:

at 100 ℃;

DOI:10.1038/1841301a0

upstream raw materials:

D-sorbitol

6-nitro-6-deoxy-D-glucitol

6,7-dideoxy-D-gluco-hept-6-enitol

((2S,3R,4S,5S)-3,4,5,6-Tetrakis-benzyloxy-tetrahydro-pyran-2-yl)-methanol

Downstream raw materials:

D-glycero-L-galacto-heptonic acid

D-glycero-D-ido-heptonic acid

lyxo-[2]Hexosulose-bis-phenylhydrazon

L-Sorbitol