3,5-DI-TERT-BUTYLBENZOIC ACID METHYL ESTER

Base Information

• Chemical Name: 3,5-DI-TERT-BUTYLBENZOIC ACID METHYL ESTER
• CAS No.: 64277-87-8
• Molecular Formula: C16H24O2
• Molecular Weight: 248.365
• Hs Code.: 2916399090
• Mol file: 64277-87-8.mol

Synonyms:3,5-Di-tert-butyl-benzoesaeure-methylester;Methyl 3,5-Di-tert-butylbenzoate;3,5-Di-tert-butylbenzoic Acid Methyl Ester;

Chemical Property of 3,5-DI-TERT-BUTYLBENZOIC ACID METHYL ESTER

Chemical Property:

• Vapor Pressure: 0.000926mmHg at 25°C
• Melting Point: 53oC
• Boiling Point: 303.5oC at 760 mmHg
• Flash Point: 136.7oC
• PSA: 26.30000
• Density: 0.952g/cm3
• LogP: 4.06820
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

98%,99%, ^*data from raw suppliers

Methyl 3,5-Di-tert-butylbenzoate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3,5-DI-TERT-BUTYLBENZOIC ACID METHYL ESTER

There total 5 articles about 3,5-DI-TERT-BUTYLBENZOIC ACID METHYL ESTER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

methanol (67-56-1) + 3,5-di-tert-butylbenzoic acid (16225-26-6) → methyl 3,5-di(tert-butyl)benzoate (64277-87-8)

Guidance literature:

With thionyl chloride; at 20 ℃;

DOI:10.1021/ma021075l

Reference yield:

methanol (67-56-1) + 3,5-Di-tert-butylbenzaldehyde (17610-00-3) + sodium methylate (124-41-4) + benzaldehyde (100-52-7) → benzoic acid methyl ester (93-58-3,5705-52-2,80226-58-0) + methyl 3,5-di(tert-butyl)benzoate (64277-87-8)

Guidance literature:

With gold supported on titanium dioxide; oxygen; at 20 ℃; under 760.051 Torr;

DOI:10.1002/anie.200906977

Reference yield:

methyl iodide (74-88-4) + 3,5-di-tert-butylbenzoic acid (16225-26-6) → methyl 3,5-di(tert-butyl)benzoate (64277-87-8)

Guidance literature:

With potassium carbonate; In N-methyl-acetamide; water;

upstream raw materials:

methanol

3,5-di-tert-butylbenzoic acid

3, 5-di-tert-butyltoluene

methyl iodide

Downstream raw materials:

tris(3,5-di-tert-butylphenyl)methanol

methanol

3,5-di-tert-butylbenzoic acid

2-(3',5'-di-tert-butyl)phenylindene

Refernces

• 1、 -. "ORGANIC IRIDIUM COMPLEX FOR ORGANIC ELECTROLUMINESCENCE ELEMENT". Paragraph 0035. . Retrieved 2016/12/01.
• 2、 Laursen, Anders B.,Hojholt, Karen T.,Lundegaard, Lars F.,Simonsen, Soren B.,Helveg, Stig,Schueth, Ferdi,Paul, Michael,Grunwaldt, Jan-Dierk,Kegns, Soren,Christensen, Claus H.,Egeblad, Kresten. "Substrate size-selective catalysis with zeolite-encapsulated gold nanoparticles". supporting information; experimental part. p. 3504 - 3507. Retrieved 2010/08/05.