Molybdenum, pentacarbonyl(trimethylphosphite-p)-

Base Information

• Chemical Name: Molybdenum, pentacarbonyl(trimethylphosphite-p)-
• CAS No.: 15631-20-6
• Molecular Formula: C8H9 Mo O8 P
• Molecular Weight: 360.068
• Mol file: 15631-20-6.mol

Synonyms:Molybdenum, pentacarbonyl(trimethylphosphite-p)-;Molybdenum, pentacarbonyl(trimethylphosphite-P)-, (OC-6-22)-;15631-20-6

Chemical Property of Molybdenum, pentacarbonyl(trimethylphosphite-p)-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 3
• Exact Mass: 362.916733
• Heavy Atom Count: 18
• Complexity: 176

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CO[PH+](OC)OC.[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Mo]

Technology Process of Molybdenum, pentacarbonyl(trimethylphosphite-p)-

There total 1 articles about Molybdenum, pentacarbonyl(trimethylphosphite-p)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

[Mo3(η5-cyclopentadienyl)2(μ3-methylidyne)(μ-dicyclohexylphosphide)(CO)6(P(OMe)3)] (1286281-97-7) → pentacarbonyltrimethylphosphitemolybdenum(0) (15631-20-6) + [Mo2(η5-cyclopentadienyl)2(μ-methylidyne)(μ-dicyclohexylphosphide)(CO)] (1286281-98-8)

Guidance literature:

In toluene; under N2; toluene soln. of Mo complex refluxed for 15 min; solvent removed under vac.; column chromd. (alumina, CH2Cl2-petroleum ether 1:3) at 288 K; rose fraction collected; solvent removed under vac.; elem. anal.;

DOI:10.1021/om1011819

Reference yield:

pentacarbonyltrimethylphosphitemolybdenum(0) (15631-20-6) + trimethylamine-N-oxide (1184-78-7) + phosphorous acid trimethyl ester (121-45-9) → bis(trimethylphosphite)molybdenum tetracarbonyl (15631-22-8) + carbon dioxide (124-38-9,18923-20-1) + trimethylamine (75-50-3)

Guidance literature:

In dichloromethane; acetonitrile; 26°C, CH2Cl2/CH3CN (1:1 v/v) soln.; progress of reaction monitored by IR spectroscopy; Kinetics;

upstream raw materials:

[Mo3(η5-cyclopentadienyl)2(μ3-methylidyne)(μ-dicyclohexylphosphide)(CO)6(P(OMe)3)]

Downstream raw materials:

bis(trimethylphosphite)molybdenum tetracarbonyl

carbon dioxide

trimethylamine