2,2'-Bis[(prop-2-en-1-yl)oxy]-1,1'-biphenyl

Base Information

Chemical Name:2,2'-Bis[(prop-2-en-1-yl)oxy]-1,1'-biphenyl
CAS No.:73429-23-9
Molecular Formula:C18H18O2
Molecular Weight:266.34
Hs Code.:
DSSTox Substance ID:DTXSID20508119
Nikkaji Number:J1.392.008G
Wikidata:Q82364830

Synonyms:73429-23-9;2,2'-Bis[(prop-2-en-1-yl)oxy]-1,1'-biphenyl;SCHEMBL7764770;DTXSID20508119

Suppliers and Price of 2,2'-Bis[(prop-2-en-1-yl)oxy]-1,1'-biphenyl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2,2'-Bis[(prop-2-en-1-yl)oxy]-1,1'-biphenyl

Chemical Property:

XLogP3:4.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:7
Exact Mass:266.130679813
Heavy Atom Count:20
Complexity:270

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C=CCOC1=CC=CC=C1C2=CC=CC=C2OCC=C

Technology Process of 2,2'-Bis[(prop-2-en-1-yl)oxy]-1,1'-biphenyl

There total 1 articles about 2,2'-Bis[(prop-2-en-1-yl)oxy]-1,1'-biphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: 67-56-1
methanol

: 201230-82-2
carbon monoxide

: 151414-76-5
o-(prop-2-enyloxy)phenylboronic acid

: 1242412-59-4
C₁₈H₁₈O₂

: 6282-42-4
methyl 2-allyloxybenzoate

: 73429-23-9
2,2′-di(allyloxy)-biphenyl

Guidance literature:: With palladium diacetate; triphenylphosphine; p-benzoquinone; at 20 ℃; for 2h; under 760.051 Torr;
DOI:10.1002/adsc.200900836

Reference yield: 81.0%

: 73429-23-9
2,2′-di(allyloxy)-biphenyl

: 528-43-8
Magnolol

Guidance literature:: With antimonypentachloride; In dichloromethane; at -78 ℃;

Reference yield:

: 73429-23-9
2,2′-di(allyloxy)-biphenyl

: (S,S)-(4,8-dipropyl-5,7-dioxa-6-phosphadibenzo[a,c]cyclohepten-6-yl)bis(1-phenylethyl)amine

Guidance literature:: Multi-step reaction with 3 steps

1.1: 80 percent / 24 h / 190 °C / ambient pressure

2.1: 81 percent / H₂ / Pd/C / methanol / 2 h / 760 Torr

3.1: triethylamine; PCl₃ / tetrahydrofuran / 3 h / 20 °C

3.2: 53 percent / tetrahydrofuran / 20 °C

With hydrogen; triethylamine; phosphorus trichloride; palladium on activated charcoal; In tetrahydrofuran; methanol; 1.1: Claisen rearrangement;
DOI:10.1021/jo049359m