Technology Process of Trigermane
There total 13 articles about Trigermane which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
not given;
reaction of diluted HCl (1 : 4) with Ge Mg alloy in H2 atmosphere;; condensing and fractionating in a Stock apparatus; transition temperature : -63 - -60 °C;;
DOI:10.1021/ja01668a015
- Guidance literature:
-
With
trimethylamine;
In
neat (no solvent);
under N2 or in vac., Me3N : GeH3Br > 1, Me3N condensed onto GeH3Br at -196°C, warmed to -78°C, mixed, then warmed to -63°C; volatile materials removed at -63°C, small quantities of GeH4, Ge2H6 and Ge3H8 (2-8%);
DOI:10.1016/S0020-1693(00)85155-5
- Guidance literature:
-
With
hydrogenchloride;
In
hydrogenchloride;
byproducts: GeCl2; heating suspension of (GeH2)x in HCl-soln. under H2-atmosphere to boiling temp.;; fractional distillation;;
