(E)-Phenyl-1-propenylsulfide

Base Information

• Chemical Name: (E)-Phenyl-1-propenylsulfide
• CAS No.: 22103-05-5
• Molecular Formula: C9H10 S
• Molecular Weight: 150.244
• Hs Code.: 2930909090
• NSC Number: 135399
• Nikkaji Number: J181.297A,J552.655H
• Mol file: 22103-05-5.mol

Synonyms:(E)-Phenyl-1-propenylsulfide;[(E)-prop-1-enyl]sulfanylbenzene;15436-04-1;22103-05-5;NSC135399;prop-1-enylsulfanylbenzene;(1-Propenyl)phenyl sulfide;(E)-1-(Phenylthio)propene;Benzene, (1-propenylthio)-;(E) Phenyl-1-propenylsulfide;SCHEMBL7661995;SCHEMBL18324553;phenyl (1E)-1-propenyl sulfide;QAKDINZUNLASCF-KRXBUXKQSA-N;[(1E)-1-Propenylsulfanyl]benzene;[(E)-prop-1-enyl]sulfanyl-benzene;[(1E)-1-Propenylsulfanyl]benzene #;NSC-135399

Chemical Property of (E)-Phenyl-1-propenylsulfide

Chemical Property:

• Vapor Pressure: 0.151mmHg at 25°C
• Boiling Point: 222.4°Cat760mmHg
• Flash Point: 82.1°C
• PSA: 25.30000
• Density: 1.02g/cm³
• LogP: 3.31230
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 150.05032149
• Heavy Atom Count: 10
• Complexity: 101

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC=CSC1=CC=CC=C1
• Isomeric SMILES: C/C=C/SC1=CC=CC=C1

Technology Process of (E)-Phenyl-1-propenylsulfide

There total 42 articles about (E)-Phenyl-1-propenylsulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

(1S,2S)-1-Phenylsulfanyl-1-tributylstannanyl-propan-2-ol → phenyl (E)-propenyl sulphide (16336-50-8,22103-05-5,15436-04-1)

Guidance literature:

With perchloric acid; In methanol; water;

DOI:10.1016/S0040-4039(01)01990-6

Reference yield: 77.0%

1-bromo-1-propene (590-14-7) + sodium thiophenolate (930-69-8) → 1-(phenylthio)-1-propene (22103-05-5)

Guidance literature:

With (2,2'-bipyridine)nickel(II) dibromide; In 1,2-dimethoxyethane; at 120 ℃; for 48h;

DOI:10.1021/jo00356a024

Reference yield: 77.0%

propylene sulphide (1072-43-1) + 2-carboxybenzene diazonium chloride (4661-46-5) → 1-(phenylthio)-1-propene (22103-05-5)

Guidance literature:

With methyloxirane; In 1,2-dichloro-ethane; for 1h; Heating;

DOI:10.1016/S0040-4039(01)81261-2

upstream raw materials:

thiophenol

prop-1-yne

methyl magnesium iodide

(E)-(phenylthio)ethenyl methyl selenide

Downstream raw materials:

(E)-1-propenyl phenyl sulfone

1-Phenylmercapto-2-aethylmercapto-propan

(Z)-2-(phenylthio)-3-methyl-4-oxo-6-methyl-2,3,4,5,6,7-hexahydrobenzofuran

(E)-2-(phenylthio)-3-methyl-4-oxo-6-methyl-2,3,4,5,6,7-hexahydrobenzofuran