Diiodoplatinum;pyridine

Base Information

• Chemical Name: Diiodoplatinum;pyridine
• CAS No.: 15227-44-8
• Molecular Formula: C₁₀H₁₀I₂N₂Pt
• Molecular Weight: 607.092
• Mol file: 15227-44-8.mol

Synonyms:

Chemical Property of Diiodoplatinum;pyridine

Chemical Property:

• Vapor Pressure: 28.3mmHg at 25°C
• Boiling Point: 106.4°Cat760mmHg
• Flash Point: 4.4°C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 606.85814
• Heavy Atom Count: 15
• Complexity: 97.6

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=NC=C1.C1=CC=NC=C1.I[Pt]I

Technology Process of Diiodoplatinum;pyridine

There total 21 articles about Diiodoplatinum;pyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

cis-diiodobis(pyridine)platinum(II) (15227-45-9,32162-03-1,15227-44-8) → trans-platinum(I)2(pyridine)2 (15227-44-8,15227-45-9,32162-03-1)

Guidance literature:

In benzene; boiling in benzene-soln.;

Reference yield: 91.0%

potassium tetrachloroplatinate(II) (10025-99-7) → cis-diiodobis(pyridine)platinum(II) (15227-45-9,32162-03-1,15227-44-8)

Guidance literature:

With KI; C₅H₅N; In water; dissolving of K2(PtCl4) in water and addn. to a KI soln. in water, filtn., addn. of filtrate with stirring to an excess of pyridine in water, stirring for 30 min; filtn., washing (water, ethanol), drying under vacuum;

Reference yield: 72.0%

platinum(II) iodide (7790-39-8) → trans-platinum(I)2(pyridine)2 (15227-44-8,15227-45-9,32162-03-1) + cis-diiodobis(pyridine)platinum(II) (15227-45-9,32162-03-1,15227-44-8)

Guidance literature:

With pyridine; In dichloromethane; stirring (room temp., 5 h), filtration, evapn. to dryness, treatment with i-PrOH (mixt. of products), dissolving (acetone/water 1:10), addn. of pyridine, refluxing (3 h), pptn.; filtration off, washing (i-PrOH);

DOI:10.1039/DT9890001011

upstream raw materials:

pyridine

cis-(N,N-dimethyl-ethylenediamine)diiodoplatinum(II)

thallous 2,3,5,6-tetrafluorobenzoate

Hexafluorobenzene

Downstream raw materials:

trans-platinum(I)2(pyridine)2

(pyridine)4platinum(II) I₂