9-Phenanthrenamine, N,N-dimethyl-

Base Information

Chemical Name:9-Phenanthrenamine, N,N-dimethyl-
CAS No.:87884-68-2
Molecular Formula:C16H15N
Molecular Weight:221.302
Hs Code.:
DSSTox Substance ID:DTXSID90447506
Nikkaji Number:J1.160.434J

Synonyms:9-Phenanthrenamine, N,N-dimethyl-;87884-68-2;SCHEMBL3281012;DTXSID90447506;N,N-Dimethylphenanthrene-9-amine

Suppliers and Price of 9-Phenanthrenamine, N,N-dimethyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of 9-Phenanthrenamine, N,N-dimethyl-

Chemical Property:

XLogP3:4.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:221.120449483
Heavy Atom Count:17
Complexity:260

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CN(C)C1=CC2=CC=CC=C2C3=CC=CC=C31

Technology Process of 9-Phenanthrenamine, N,N-dimethyl-

There total 1 articles about 9-Phenanthrenamine, N,N-dimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2510-55-6
9-cyanophenanthrene

: 124-40-3
dimethyl amine

: 87884-68-2
N,N'-dimethyl-9-phenanthrenamine

: 75-31-0
isopropylamine

Guidance literature:: Quantum yield;
DOI:10.1021/ja00313a039

Reference yield: 48.0%

: 5123-13-7
5,5-dimethyl-2-phenyl-1,3,2-dioxaborinane

: 87884-68-2
N,N'-dimethyl-9-phenanthrenamine

: 85-01-8
phenanthrene

: 844-20-2
9-phenylphenanthrene

Guidance literature:: With 1,3-bis(2,4,6-trimethylphenyl)4,5-dimethyl-1,3-dihydro-2H-imidazol-2-ylidene; magnesium; nickel dibromide; In tetrahydrofuran; at 135 ℃; for 36h; Inert atmosphere; Sealed tube; Schlenk technique;
DOI:10.1021/jacs.8b08779

Reference yield:

: 87884-68-2
N,N'-dimethyl-9-phenanthrenamine

: 2-formyl-N-methyl-3-phenyldibenzo[de,g]quinoline

Guidance literature:: Multi-step reaction with 2 steps

1.1: nBuLi / hexane; diethyl ether / 96 h / 20 °C

1.2: 61 percent / iodine / diethyl ether / 1 h

2.1: 81 percent / Ph3CH / {(dmpa)Pd(μ-I)}2 / chlorobenzene / 58 h / 150 °C

With n-butyllithium; triphenylmethane; {(dmpa)Pd(μ-I)}2; In diethyl ether; hexane; chlorobenzene; 1.1: Metallation / 1.2: Iodination / 2.1: Cyclization;
DOI:10.1002/(sici)1099-0690(199908)1999:8<1957::aid-ejoc1957>3.0.co;2-i