(Chloromethyl)(dimethyl)silanol

Base Information

• Chemical Name: (Chloromethyl)(dimethyl)silanol
• CAS No.: 18191-32-7
• Molecular Formula: C3H9ClOSi
• Molecular Weight: 124.642
• NSC Number: 139829
• DSSTox Substance ID: DTXSID60300891
• Nikkaji Number: J1.580.378I
• Wikidata: Q82044307
• Mol file: 18191-32-7.mol

Synonyms:18191-32-7;(chloromethyl)(dimethyl)silanol;(chloromethyl)dimethylsilanol;NSC139829;SCHEMBL5312771;DTXSID60300891;AKOS006384030;NSC-139829

Chemical Property of (Chloromethyl)(dimethyl)silanol

Chemical Property:

• Vapor Pressure: 2.67mmHg at 25°C
• Boiling Point: 139.4°Cat760mmHg
• Flash Point: 38.1°C
• Density: 1.015g/cm³
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 124.0111191
• Heavy Atom Count: 6
• Complexity: 46.1

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(CCl)O

Technology Process of (Chloromethyl)(dimethyl)silanol

There total 4 articles about (Chloromethyl)(dimethyl)silanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzyl chloromethyldimethylsilyl ether (108181-71-1) → (chloromethyl)dimethylsilanol (18191-32-7) + benzyl alcohol (100-51-6,185532-71-2)

Guidance literature:

at 37 ℃; Rate constant; 45percent acetone-containing aqueous buffer;

DOI:10.1016/S0040-4020(01)90600-3

Reference yield:

chloromethyldimethylsilane (3144-74-9) → Trimethylsilanol (1066-40-6) + (chloromethyl)dimethylsilanol (18191-32-7)

Guidance literature:

DOI:10.1021/ja01510a066

Reference yield:

Chloro(chloromethyl)dimethylsilane (1719-57-9) → (chloromethyl)dimethylsilanol (18191-32-7) + 1,3-Bis(chloromethyl)-1,1,3,3-tetramethyldisiloxane (2362-10-9)

Guidance literature:

With water; triethylamine; In tetrahydrofuran; at 20 ℃; for 0.1h; Reagent/catalyst; Solvent; Temperature;

DOI:10.1007/s00706-014-1366-7

upstream raw materials:

benzyl chloromethyldimethylsilyl ether

chloromethyldimethylsilane

Chloro(chloromethyl)dimethylsilane

N-[(chloromethyl)dimethylsilyl]dimethylamine

Downstream raw materials:

methanol

1-chloromethylpentamethyldisiloxane

1,3-Bis(chloromethyl)-1,1,3,3-tetramethyldisiloxane

(chloromethyl)methoxydimethylsilane