Borinic acid, bis(4-chlorophenyl)-

Base Information

• Chemical Name: Borinic acid, bis(4-chlorophenyl)-
• CAS No.: 89566-59-6
• Molecular Formula: C12H9BCl2O
• Molecular Weight: 250.92
• Mol file: 89566-59-6.mol

Synonyms:

Chemical Property of Borinic acid, bis(4-chlorophenyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Borinic acid, bis(4-chlorophenyl)-

There total 11 articles about Borinic acid, bis(4-chlorophenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

B-(2-aminoethoxy)bis(4-chlorophenyl)borane (61733-90-2) → di-(p-chlorophenyl)borinic acid (89566-59-6)

Guidance literature:

With hydrogenchloride; In methanol; acetone; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1039/c5cc06177f

Reference yield: 22.0%

cyclotriboric acid trimethyl ester (102-24-9) + (4-chlorphenyl)magnesium bromide (873-77-8) → methanol (67-56-1) + di-(p-chlorophenyl)borinic acid (89566-59-6)

Guidance literature:

With water; byproducts: BrMgOH;

DOI:10.1021/ja01553a022

Reference yield:

(4-chlorphenyl)magnesium bromide (873-77-8) → di-(p-chlorophenyl)borinic acid (89566-59-6)

Guidance literature:

Multistep reaction; (i) Ph₂NBCl₂, Et₂O, benzene, (ii) aq. HCl;

DOI:10.1039/jr9610004909

upstream raw materials:

(4-chlorphenyl)magnesium bromide

triisobutyl borate

Trimethyl borate

cyclotriboric acid trimethyl ester

Downstream raw materials:

4'-(4-chlorophenyl)acetophenone

[(C₆H₅)Co((ONC(CH₃)C(CH₃)NOB(C₆H₄Cl)2)2)(C₃H₃N₂CH₃)]

[(H₃C)Co((ONC(CH₃)C(CH₃)NOB(C₆H₄Cl)2)2)(C₅H₅N)]

[(CH₃)Co((ONC(CH₃)C(CH₃)NOB(C₆H₄Cl)2)2)(H₂O)]

Refernces

• 1、 Richard, Jimmy,Birepinte, Mélodie,Charbonnier, Jean Baptiste,Liautard, Virginie,Pinet, Sandra,Pucheault, Mathieu. "Borinic Acids via Direct Arylation of Amine-Borane Complexes: An Air- and Water-Stable Boron Source". . p. 736 - 744. Retrieved 2017/02/15.
• 2、 -. "Compounds for the Treatment of Periodontal Disease". Page/Page column 64. . Retrieved 2008/06/13.