di-n-Butylethylamine

Base Information

• Chemical Name: di-n-Butylethylamine
• CAS No.: 4458-33-7
• Molecular Formula: C10H23 N
• Molecular Weight: 157.299
• Hs Code.: 2921199090
• European Community (EC) Number: 224-711-2
• UNII: L70Q7EKN2C
• DSSTox Substance ID: DTXSID30196228
• Nikkaji Number: J205.848K
• Wikidata: Q83069299
• Mol file: 4458-33-7.mol

Synonyms:di-n-Butylethylamine;4458-33-7;N-Ethyldibutylamine;n-butyl-n-ethylbutan-1-amine;dibutylethylamine;Ethyl di-N-butylamine;1-Butanamine, N-butyl-N-ethyl-;DIBUTYL(ETHYL)AMINE;L70Q7EKN2C;EINECS 224-711-2;ethyldibutylamine;dibutyl ethylamine;Dibutylamine, N-ethyl-;UNII-L70Q7EKN2C;Di-n-butylethylamine, 97%;SCHEMBL217114;n-Butyl-N-ethyl-1-butanamine;DTXSID30196228;n-Butyl-N-ethyl-1-butanamine #;ADAL1185607;FT-0625172

Chemical Property of di-n-Butylethylamine

Chemical Property:

• Vapor Pressure: 0.795mmHg at 25°C
• Refractive Index: n20/D 1.4220(lit.)
• Boiling Point: 182.8°Cat760mmHg
• PKA: 9.99±0.50(Predicted)
• Flash Point: 52.6°C
• PSA: 3.24000
• Density: 0.783g/cm³
• LogP: 2.90850
• Storage Temp.: 2-8°C
• XLogP3: 3.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 7
• Exact Mass: 157.183049738
• Heavy Atom Count: 11
• Complexity: 63.3

Purity/Quality:

98%Min ^*data from raw suppliers

Di-n-butylethylamine 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 10-34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCCN(CC)CCCC
• Uses: Ethyldibutylamine is a useful reagent for organic synthesis.

Technology Process of di-n-Butylethylamine

There total 24 articles about di-n-Butylethylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

dibutylamine (111-92-2) + acetonitrile (75-05-8,26809-02-9) → di-n-butylethylamine (4458-33-7)

Guidance literature:

With palladium 10% on activated carbon; ammonium acetate; hydrogen; In methanol; at 20 ℃; for 24h; under 760.051 Torr;

DOI:10.1039/c1ob06303k

Reference yield: 60.7%

ethylamine (75-04-7,85404-22-4) + N-butylamine (109-73-9,85404-21-3) → tributyl-amine (102-82-9) + N-ethylbutylamine (13360-63-9) + N,N-diethylbutylamine (4444-68-2) + di-n-butylethylamine (4458-33-7) + dibutylamine (111-92-2) + diethylamine (109-89-7) + triethylamine (121-44-8)

Guidance literature:

With hydrogen; at 200 ℃; under 6000.6 Torr; Reagent/catalyst; Temperature;

DOI:10.1007/s11164-012-0790-8

Reference yield:

triethylamine (121-44-8) → N-ethylbutylamine (13360-63-9) + N,N-diethylbutylamine (4444-68-2) + di-n-butylethylamine (4458-33-7) + ethylamine (75-04-7,85404-22-4) + diethylamine (109-89-7)

Guidance literature:

With palladium on activated charcoal; at 200 ℃; for 5h; under 3750.38 Torr; Reagent/catalyst; Temperature; Catalytic behavior; Inert atmosphere;

DOI:10.1039/c8ra08316a

upstream raw materials:

tributyl-amine

ethanol

ethylamine

butan-1-ol

Downstream raw materials:

N-(n-butyl)aniline

N-ethyl-N-phenylamine

Refernces

• 1、 Xu, Lu-Feng,Huang, Jia-Min,Qian, Chao,Chen, Xin-Zhi,Feng, Lie,Chen, Yun-Bin,He, Chao-Hong. "The synthesis of N-ethyl-n-butylamine by amines disproportionation". . p. 2697 - 2704. Retrieved 2013/07/26.
• 2、 Kometani,Shiotani,Mitsuhashi. "On the cleavage of tertiary amines with ethyl chloroformate". . p. 342 - 349. Retrieved 2007/10/04.