1-Propene, 1-ethoxy-2-methyl-

Base Information

• Chemical Name: 1-Propene, 1-ethoxy-2-methyl-
• CAS No.: 927-61-7
• Molecular Formula: C6H12O
• Molecular Weight: 100.161
• DSSTox Substance ID: DTXSID80453292
• Nikkaji Number: J935.377A
• Mol file: 927-61-7.mol

Synonyms:927-61-7;1-Propene, 1-ethoxy-2-methyl-;1-ethoxy-2-methylpropene;1-ETHOXY-2-METHYLPROP-1-ENE;1-Ethoxy-2-methyl-propene;Ethylisobutenyl ether;dimethyl vinyl ethyl ether;SCHEMBL295231;DTXSID80453292;IHCLUFSKPOJGDC-UHFFFAOYSA-N

Chemical Property of 1-Propene, 1-ethoxy-2-methyl-

Chemical Property:

• Vapor Pressure: 50.833mmHg at 25°C
• XLogP3: 2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 100.088815002
• Heavy Atom Count: 7
• Complexity: 60.6

Purity/Quality:

99.3% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOC=C(C)C

Technology Process of 1-Propene, 1-ethoxy-2-methyl-

There total 11 articles about 1-Propene, 1-ethoxy-2-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

isobutyraldehyde diethyl acetal (1741-41-9) → 1-ethoxy-2-methylpropene (927-61-7)

Guidance literature:

With phosphoric acid;

Reference yield:

2-methylprop-1-enyl chloride (513-37-1) + lithium ethoxide (2388-07-0) → 2-methyl-2-heptene (627-97-4) + 1-ethoxy-2-methylpropene (927-61-7)

Guidance literature:

With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In tetrahydrofuran; diethyl ether; at -78 ℃; for 6h;

DOI:10.1016/0022-328X(93)83391-8

Reference yield:

isobutyraldehyde (78-84-2) + orthoformic acid triethyl ester (122-51-0) → 1-ethoxy-2-methylpropene (927-61-7)

Guidance literature:

Multistep reaction; (i) NH₄Cl, (ii) H₃PO₄;

upstream raw materials:

isobutyraldehyde diethyl acetal

dianilunium sulphate

2-methylprop-1-enyl chloride

sodium ethanolate

Downstream raw materials:

isobutyraldehyde

1,1,3,3-tetraethoxy-2,2-dimethylpropane

ethyl N-tosyl-2-methylpropanimidate

1,1,3-Triethoxy-2,2-dimethyl-3-phenyl-propan