Acridan, 10-methyl-

Base Information

• Chemical Name: Acridan, 10-methyl-
• CAS No.: 4217-54-3
• Molecular Formula: C14H13N
• Molecular Weight: 195.264
• Mol file: 4217-54-3.mol

Synonyms:

Chemical Property of Acridan, 10-methyl-

Chemical Property:

• Vapor Pressure: 0.000311mmHg at 25°C
• Melting Point: 93-95 °C
• Boiling Point: 373.7°Cat760mmHg
• PKA: 1.63±0.20(Predicted)
• Flash Point: 161.7°C
• PSA: 4.93000
• Density: 1.15g/cm³
• LogP: 2.35220

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Acridan, 10-methyl-

There total 190 articles about Acridan, 10-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

10-methylacridinium perchlorate (26456-05-3) + nitrobenzene (98-95-3,26969-40-4) → 9,10-dihydro-10-methylacridine (4217-54-3) + aniline (62-53-3)

Guidance literature:

With perchloric acid; In water; acetonitrile; at 24.9 ℃; for 28h; Product distribution; Quantum yield; Mechanism; Irradiation; other nitrobenzenes, nitrosobenzene, or phenylhydroxylamine; effect of concn. of HClO₄;

DOI:10.1246/bcsj.65.831

Reference yield: 73.0%

benzyldiisopropylamine (34636-09-4) + 10-methylacridinium perchlorate (26456-05-3) → 9,10-dihydro-10-methylacridine (4217-54-3) + 10-methyl-9, 10-dihydro-9-acridinone (719-54-0) + benzaldehyde (100-52-7) + 9-(Benzyl-isopropyl-amino)-10-methyl-acridinium; perchlorate

Guidance literature:

With oxygen; In acetonitrile; for 24h; Ambient temperature;

DOI:10.1246/bcsj.65.55

Reference yield: 58.0%

N-ethyl-N-methylbenzylamine (4788-37-8) + 10-methylacridinium perchlorate (26456-05-3) → 9,10-dihydro-10-methylacridine (4217-54-3) + 10-methyl-9, 10-dihydro-9-acridinone (719-54-0) + 9-(Ethyl-methyl-amino)-10-methyl-acridinium; perchlorate + 9-(Benzyl-methyl-amino)-10-methyl-acridinium; perchlorate

Guidance literature:

With oxygen; In acetonitrile; for 24h; Further byproducts given; Ambient temperature;

DOI:10.1246/bcsj.65.55

upstream raw materials:

N-benzylpyrrolidine

10-methylacridinium perchlorate

1-propyl-1,4-dihydronicotinamide

N-methylacridinium iodide

Downstream raw materials:

9-triphenylsilyl-10-methylacridane

10-methyl-9, 10-dihydro-9-acridinone

10-methylacridinium chloride

10H-acridin-9-one

Refernces

• 1、 Fukuzumi, Shunichi,Imahori, Hiroshi,Okamoto, Ken,Yamada, Hiroko,Fujitsuka, Mamoru,Ito, Osamu,Guldi, Dirk M.. "Uphill photooxidation of NADH analogues by hexyl viologen catalyzed by zinc porphyrin-linked fullerenes". . p. 1903 - 1908. Retrieved 2002.
• 2、 Yuan, Lung-Chi,Bruice, Thomas C.. "Redox Reactions of a Tetrahydro-/Hexahydropyridodipyrimidine Tetrone Couple. A High vs. Low Potential 5-Carba-5-deazaflavin Mimic". . p. 1530 - 1531. Retrieved 1984.
• 3、 Fukuzumi, Shunichi,Yuasa, Junpei,Satoh, Naoya,Suenobu, Tomoyoshi. "Scandium ion-promoted photoinduced electron transfer from electron donors to acridine and pyrene. Essential role of scandium ion in photocatalytic oxygenation of hexamethylbenzene". . p. 7585 - 7594. Retrieved 2004.
• 4、 Mondal, Pradip Kumar,Tiwari, Sandip Kumar,Singh, Pushpendra,Pandey, Ganesh. "Direct Arylation of Distal and Proximal C(sp3)-H Bonds of t-Amines with Aryl Diazonium Tetrafluoroborates via Photoredox Catalysis". . p. 17184 - 17196. Retrieved 2021/12/02.
• 5、 Kolodziejczak, Krystian,Murphy, John A.,Stewart, Alexander J.,Tuttle, Tell. "Radical and ionic mechanisms in rearrangements of o-tolyl aryl ethers and amines initiated by the Grubbs-stoltz reagent, et3SiH/KOtbu". . . Retrieved 2021/12/04.